183559-62-8Relevant articles and documents
Atom-bridged intermediates in N- and P-atom transfer reactions
Johnson,Lee,Odom,Davis,Cummins
, p. 87 - 91 (2008/10/09)
Formal N-atom insertion into the metal metal triple bond of the diamagnetic compound 1, which has been known for over twenty years, results in the paramagnetic, nitridobridged molecule 2. The characterization of three such N- and P-atom bridged species is described, and their role as intermediates in three-electron atom transfer reactions is highlighted.