183621-32-1

Basic information

• Product Name: Benzene, 1-fluoro-4-(3-phenyl-1-propenyl)-, (E)-
• CAS NO: 183621-32-1
• Molecular Formula: C15H13F
• Molecular Weight: 212.267
• Mol File: 183621-32-1.mol
• Article Data: 21

Chemical Properties

• CAS DataBase Reference: Benzene, 1-fluoro-4-(3-phenyl-1-propenyl)-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-fluoro-4-(3-phenyl-1-propenyl)-, (E)-(183621-32-1)
• EPA Substance Registry System: Benzene, 1-fluoro-4-(3-phenyl-1-propenyl)-, (E)-(183621-32-1)

Safety Data

• Hazardous Substances Data: 183621-32-1(Hazardous Substances Data)

Upstream product

• 5724-03-8 1-(4-fluorophenyl)allyl alcohol 
• 111928-10-0 tetraphenylphosphonium trifluoromethanesulfonate 
• 98-80-6 phenylboronic acid 
• 706-08-1 trans-1-(4-fluorophenyl)-2-nitro-ethene 
• 1539-57-7 diethyl 2,6-dimethyl-4-benzyl-1,4-dihydropyridine-3,5-dicarboxylate 
• 459-32-5 (E)-4-fluorocinnamic acid 
• 96426-60-7 methyl (2E)-3-(4-fluorophenyl)-2-propenoate 
• 2996-92-1 phenyl trimethylsiloxane 
• 205108-06-1 (E)-3-(4'-fluorophenyl)-2-propen-1-ol acetate 
• 405-99-2 para-fluorostyrene 
• 34636-09-4 benzyldiisopropylamine 
• 89523-63-7 benzylzinc chloride 
• 87100-28-5 pinacol benzylboronate 
• 122-78-1 phenylacetaldehyde 

Downstream Products

• 42882-83-7 3-(phenyl)-5-(4-fluorophenyl)-1-p-toluenesulfonyl-1H-pyrazole 

Relevant articles and documents

Consecutive reactions of vinylic phosphonium salts with Grignard reagents catalyzed by CuBr-Ag2CO3 or CuBr-H2O

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In Situ Ring-Closing Strategy for Direct Synthesis of N-Heterocyclic Carbene Nickel Complexes and Their Application in Coupling of Allylic Alcohols with Aryl Boronic Acids

A in situ ring-closing strategy was developed for the synthesis of N-heterocyclic carbene nickel complexes. The process was carried out in air, and did not require solvent purification. The resulting nickel complexes were investigated as catalysts for the coupling of allylic alcohols with aryl boronic acids. A wide range of allylic substrates and aryl acids proved to be applicable to this catalytic system. Control experiments suggest that the Ni(0) may be the true active species in the coupling reactions. (Figure presented.).

C–C Cross-Coupling Reactions of Organosilanes with Terminal Alkenes and Allylic Acetates Using PdII Catalyst Supported on Starch Coated Magnetic Nanoparticles

Starch coated magnetic nanoparticles supported palladium catalyst has been explored to perform C–C cross coupling reactions, such as oxidative Heck coupling and Tsuji–Trost allylic coupling using organosilicon compounds as one of the coupling partners. The biopolymer coated magnetic catalyst was very easy to recover magnetically and was efficiently recycled in the subsequent batches. All the reactions were performed in air and thus the necessity of air and moisture free reaction condition is avoided. The present protocols show wide substrate scope and good yields of the products.