18611-72-8

Basic information

• Product Name: Lithium, (2,6-difluorophenyl)-
• CAS NO: 18611-72-8
• Molecular Formula: C6H3F2Li
• Molecular Weight: 120.028
• Mol File: 18611-72-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Lithium, (2,6-difluorophenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Lithium, (2,6-difluorophenyl)-(18611-72-8)
• EPA Substance Registry System: Lithium, (2,6-difluorophenyl)-(18611-72-8)

Safety Data

• Hazardous Substances Data: 18611-72-8(Hazardous Substances Data)

Upstream product

• 372-18-9 1,3-Difluorobenzene 
• 109-72-8 n-butyllithium 
• 64248-56-2 1-bromo-2,6-difluorobenzene 

Downstream Products

• 356074-75-4 1-(2,6-difluoro-phenyl)-2,3,4,5-tetrakis-(3,5-dimethyl-phenyl)-cyclopenta-2,4-dienol 
• 490038-59-0 (6-chloro-pyridin-3-yl)-(2,6-difluoro-phenyl)-methanone 
• 125173-36-6 bis(2,6-difluorophenyl)-tris(4-methylphenyl)bismuth 
• 610296-39-4 1-(2,6-difluoro-phenyl)-1,2,3,4-tetrahydro-isoquinoline 
• 610296-31-6 2-[1-(2,6-Difluoro-phenyl)-3,4-dihydro-1H-isoquinolin-2-yl]-N-(2-fluoro-benzyl)-N-indan-2-yl-acetamide 
• 13670-99-0 2,6-difluoroacetophenone 

Relevant articles and documents

Lithium diisopropylamide-mediated ortholithiations: Lithium chloride catalysis

Ortholithiations of a range of arenes mediated by lithium diisopropylamide (LDA) in THF at -78 °C reveal substantial accelerations by as little as 0.5 mol % of LiCl (relative to LDA). Substrate dependencies suggest a specific range of reactivity within wh

METHOD FOR METAL-ORGANIC PRODUCTION OF ORGANIC INTERMEDIATE PRODUCTS BY MEANS OF ARYL LITHIUM-BASES

The invention relates to a method for the production of substituted aromatic compounds by producing lithium arylene and by reacting it with suitable electrophiles. The method comprises the following steps (step 1); an aryl lithium compound ( auxiliary base'') is initially produced by reacting a halogen aromatic compound with lithium metal; said compound is subsequently (step 2) reacted for deprotonation of the aromatic substrate in order to form the corresponding lithium aromatic compound which is subsequently (step 3) reacted with a corresponding electrophile to form the desired substituted aromatic compound, see page 2 of the description.