188120-39-0

Basic information

• Product Name: (2R,3R,4S)-4-tert-butyldimethylsilyloxy-2,3-dimethylcyclohexanone
• Synonyms: (2R,3R,4S)-4-tert-butyldimethylsilyloxy-2,3-dimethylcyclohexanone
• CAS NO: 188120-39-0
• Molecular Weight: 256.461
• Mol File: 188120-39-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (2R,3R,4S)-4-tert-butyldimethylsilyloxy-2,3-dimethylcyclohexanone(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,3R,4S)-4-tert-butyldimethylsilyloxy-2,3-dimethylcyclohexanone(188120-39-0)
• EPA Substance Registry System: (2R,3R,4S)-4-tert-butyldimethylsilyloxy-2,3-dimethylcyclohexanone(188120-39-0)

Safety Data

• Hazardous Substances Data: 188120-39-0(Hazardous Substances Data)

Upstream product

• 18162-48-6 tert-butyldimethylsilyl chloride 
• 188120-33-4 [(Z)-(3R,4R,5R)-2,5-Bis-(tert-butyl-dimethyl-silanyloxy)-6,6-dimethoxy-3,4-dimethyl-hex-1-ene-1-sulfonyl]-benzene 
• 188120-25-4 (3R,4R,5R)-3,4-Dimethyl-5-trityloxymethyl-dihydro-furan-2-one 
• 188120-30-1 (3R,4R,5R)-2-Benzenesulfonylmethyl-5-dimethoxymethyl-3,4-dimethyl-2-hydroxyoxolane 
• 188120-28-7 (3R,4R,5R)-5-Dimethoxymethyl-3,4-dimethyl-dihydro-furan-2-one 
• 188120-51-6 (3R,4R,5R)-5-Hydroxymethyl-3,4-dimethyl-dihydro-furan-2-one 
• 101758-68-3 (R)-(+)-5-triphenylmethyloxymethyl-2 (5H)-furanone 
• 112837-17-9 (R)-(+)-5-(hydroxymethyl)furan-2(5H)-one 
• 188120-36-7 (4R,5R,6R)-(+)-2-Benzenesulfonyl-4-(t-butyldimethylsilyloxy)-5,6-dimethyl-2-cyclohexen-1-one 

Downstream Products

• 1026246-65-0 (2R,3R,4S)-4-(tert-Butyl-dimethyl-silanyloxy)-2,3-dimethyl-2-(3-oxo-2-trimethylsilanyl-butyl)-cyclohexanone 

Relevant articles and documents

Synthesis of dendryphiellin C, a trinor-sesquiterpene from a marine source

Enantioselective synthesis of dendryphiellin C, isolated from cultures of Dendryphiella sarina, has been achieved in a convergent way such as coupling of a C9-branched carboxylic acid 10 with a trinor-eremophilane alcohol 11. The latter was synthesized st