18955-93-6Relevant articles and documents
Ketone-directed peracid epoxidation
Armstrong,Armstrong, Alan,Barsanti,Barsanti, Paul A.,Clarke,Clarke, Paul A.,Wood,Wood, Anthony
, p. 6155 - 6158 (1994)
Ketone carbonyl groups are shown to direct the epoxidation of cyclic alkenes with higher selectivity than that displayed by esters. An 18O labelling study is used to show that a dioxirane intermediate is not involved in these reactions.
Rhenium complex-catalyzed coupling reaction of enol acetates with alcohols
Umeda, Rui,Takahashi, Yuuki,Nishiyama, Yutaka
supporting information, p. 6113 - 6116 (2015/01/09)
The reaction of enol acetates with alcohols in the presence of a catalytic amount of a rhenium complex, such as ReBr(CO)5, produced the corresponding ketones and aldehydes in moderate to good yields. It was suggested that the preparation of an ether, an intermolecular dehydrated product, was the first step of the reaction.
InCl3/Me3SiBr-catalyzed direct coupling between silyl ethers and enol acetates
Onishi, Yoshiharu,Nishimoto, Yoshihiro,Yasuda, Makoto,Baba, Akio
supporting information; experimental part, p. 2762 - 2765 (2011/08/02)
A combined Lewis acid catalyst of InCl3 and Me3SiBr promoted the direct use of enol acetates in the coupling with low-reactive silyl ethers, in which functional groups including ketones and aldehydes survived. Sterically hindered silyl ethers such as ROSiEt3, ROSiPh3, ROSit-BuMe2, and ROSii-Pr3 were also applicable.
