68908-13-4

Basic information

• Product Name: bicyclo[2.2.2]oct-5-en-2-one
• CAS NO: 68908-13-4
• Molecular Weight: 122.167
• Mol File: 68908-13-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: bicyclo[2.2.2]oct-5-en-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: bicyclo[2.2.2]oct-5-en-2-one(68908-13-4)
• EPA Substance Registry System: bicyclo[2.2.2]oct-5-en-2-one(68908-13-4)

Safety Data

• Hazardous Substances Data: 68908-13-4(Hazardous Substances Data)

Downstream Products

• 500-23-2 bicyclo<2.2.2>-octa-2,5-diene 
• 24480-76-0 1-(3'-cyclohexenyl)-3-phenyl-2-propanone 
• 18955-93-6 1-(2'-cyclohexenyl)-2-propanone 
• 24476-16-2 1-(3'-cyclohexenyl)-2-propanone 
• 94064-42-3 Bicyclo[2.2.2]octanon-⁽²⁾-p-toluolsulfonylhydrazonn 
• 931-64-6 norbornene 
• 2716-23-6 bicyclo[2.2.2]octan-2-one 
• 6688-07-9 5-hydroxybicyclo[2.2.2]oct-2-ene 
• 6688-07-9 hydroxy-5 exo bicyclo<2.2.2>octene-2 
• 75039-48-4 (Z)-N-(Bicyclo<2.2.2>oct-5-en-2-ylidene)benzenamine 
• 75039-48-4 (E)-N-(Bicyclo<2.2.2>oct-5-en-2-ylidene)benzenamine 

Relevant articles and documents

Fragmentation of Homoallylic Alkoxides. Thermolysis of Potassium 2-Substituted Bicyclooct-5-en-2-alkoxides

Thermolysis of the potassium 2-substituted bicyclooct-5-en-2-alkoxides derived from alcohols 2-17 at 90-120 deg C in hexamethylphosphoric triamide affords unsaturated ketones resulting from allylic bond cleavage.The mechanistic and synthetic aspects of this anionic fragmentation are discussed with reference to the formation of 1-(3'-cyclohexenyl)-2-alkanones 18-28 via initial heterolytic C(1),C(2)-bond cleavage in the substrate alkoxide and regioselective, intramolecular protonation of the resultant transient allylic anion.