192436-83-2

Basic information

• Product Name: 4-BROMO-N-METHOXY-N-METHYLBENZAMIDE
• Synonyms: 4-BROMO-N-METHOXY-N-METHYLBENZAMIDE;4-[Methoxy(methyl)carbamoyl]bromobenzene
• CAS NO: 192436-83-2
• Molecular Formula: C₉H₁₀BrNO₂
• Molecular Weight: 244.09
• Mol File: 192436-83-2.mol
• Article Data: 37

Chemical Properties

• Boiling Point: 351.534 °C at 760 mmHg
• Flash Point: 166.402 °C
• Appearance: /
• Density: 1.459 g/cm³
• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.5680 to 1.5720
• Storage Temp.: Sealed in dry,Room Temperature
• CAS DataBase Reference: 4-BROMO-N-METHOXY-N-METHYLBENZAMIDE(CAS DataBase Reference)
• NIST Chemistry Reference: 4-BROMO-N-METHOXY-N-METHYLBENZAMIDE(192436-83-2)
• EPA Substance Registry System: 4-BROMO-N-METHOXY-N-METHYLBENZAMIDE(192436-83-2)

Safety Data

• Hazardous Substances Data: 192436-83-2(Hazardous Substances Data)

Usage

General Description

4-BROMO-N-METHOXY-N-METHYLBENZAMIDE is a chemical compound with the molecular formula C9H10BrNO2. It is a white solid that is used in the research and development of pharmaceuticals and agrochemicals. 4-BROMO-N-METHOXY-N-METHYLBENZAMIDE has a bromine atom, a methoxy group, and a methyl group attached to a benzamide backbone. It is known for its potential as a building block in the synthesis of various drug molecules and is also used as an intermediate in organic synthesis. Its properties and structure make it valuable in the study and production of new compounds for potential pharmaceutical and agricultural applications.

InChI:InChI=1/C9H10BrNO2/c1-11(13-2)9(12)7-3-5-8(10)6-4-7/h3-6H,1-2H3

Upstream product

• 6638-79-5 N,O-dimethylhydroxylamine*hydrochloride 
• 586-75-4 4-chlorobenzoyl chloride 
• 201230-82-2 carbon monoxide 
• 589-87-7 1,4-bromoiodobenzene 
• 99-90-1 para-bromoacetophenone 
• 1380243-00-4 3-(4-bromobenzoyl) oxazolidin-2-one 
• 13939-06-5 molybdenum hexacarbonyl 
• 321970-34-7 1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonic acid 4-bromophenyl ester 
• 619-42-1 4-methoxycarbonylphenyl bromide 
• 586-76-5 4-Bromobenzoic acid 
• 1117-97-1 N,0-dimethylhydroxylamine 

Downstream Products

• 2001-29-8 1-(4-bromophenyl)-2-phenyl-ethan-1-one 
• 161581-93-7 (4-bromo-phenyl)-(3-fluoro-4-methoxy-phenyl)-methanone 
• 4160-65-0 (4-bromophenyl)(thien-2-yl)methanone 
• 1178521-37-3 C₁₂H₆BrF₂NO 
• 1186220-85-8 3-(2-(4-bromobenzoyl)phenyl)-4-trimethylsilylsydnone 
• 284665-01-6 1-(4-bromophenyl)hex-5-en-1-one 
• 2138-34-3 1-(4-bromo-phenyl)-3-dimethylamino-propan-1-one 
• 14548-45-9 (4-bromophenyl)-pyridin-3-yl-methanone 
• 1374584-06-1 (4-trifluoromethylphenyl)(4-bromophenyl)pyrid-3-yl methanol 
• 1206248-37-4 3-(4-bromobenzoyl)benzonitrile 
• 1314313-99-9 (3Z,6Z)-3-(3-(4-bromobenzoyl)benzylidene)-6-((5-tert-butyl-1H-imidazol-4-yl)methylene)piperazine-2,5-dione 
• 1385033-74-8 C₁₄H₉BrO₂ 
• 72053-00-0 1-(4-bromophenyl)-2-(pyridin-2-yl)ethanone 
• 1435892-97-9 2-(4-bromophenyl)-4H-quinolizin-4-one 

Relevant articles and documents

Poly(vinyl ketone)s by controlled boron group transfer polymerization (BGTP)

(Figure Presented) Boron can do it! Readily prepared catecholboron enolates act as regulators in the controlled radical polymerization of alkyl and aryl vinyl ketones. Control is achieved by an unprecedented reversible radical boron group transfer (BGT) between enoyl radicals (see scheme). Polymers with M n-1 and a polydispersity index of 1.3 can be obtained by this process.

Rhoda-Electrocatalyzed Bimetallic C?H Oxygenation by Weak O-Coordination

Rhodium-electrocatalyzed arene C?H oxygenation by weakly O-coordinating amides and ketones have been established by bimetallic electrocatalysis. Likewise, diverse dihydrooxazinones were selectively accessed by the judicious choice of current, enabling twofold C?H functionalization. Detailed mechanistic studies by experiment, mass spectroscopy and cyclovoltammetric analysis provided support for an unprecedented electrooxidation-induced C?H activation by a bimetallic rhodium catalysis manifold.

Fluoro-Substituted Methyllithium Chemistry: External Quenching Method Using Flow Microreactors

The external quenching method based on flow microreactors allows the generation and use of short-lived fluoro-substituted methyllithium reagents, such as fluoromethyllithium, fluoroiodomethyllithium, and fluoroiodostannylmethyllithium. Highly chemoselective reactions have been developed, opening new opportunities in the synthesis of fluorinated molecules using fluorinated organometallics.