1928-61-6Relevant articles and documents
A method for preparing 2, 4 - dichlorophenoxyacetic acid (by machine translation)
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Paragraph 0038; 0039, (2018/09/08)
The invention provides a 2, 4 - dichlorophenoxyacetic acid preparation method, comprises the following steps: A) halogenated acetate with 2, 4 - dichlorophen salt reaction, to obtain 2, 4 - dichlorophenoxy ester; B) 2, 4 - dichlorophenoxy ester under the effects of catalyst hydrolysis reaction, to obtain 2, 4 - dichloro acid; said catalyst is selected from a polyether, a crown ether, quaternary ammonium salt, tertiary amine, [...], pyridine, titanate, inorganic acid, in organic acid one or more. The invention by halogenated acetate with 2, 4 - dichlorophen salt obtained by reaction of 2, 4 - dichlorophenoxy ester, and then in particular under the action of catalyst by hydrolysis reaction of the 2, 4 - dichloro acid. The invention specific reaction line combined with a specific catalyst such that the final preparation to obtain 2, 4 - dichlorophenoxyacetic acid purity and yield is relatively high, few by-products, the reaction route is simple, and is favorable for application. (by machine translation)
ALLYL ESTERS OF AROXYACETIC ACIDS AND THEIR REACTION WITH TRIETHYLSILANE
Voronkov, M. G.,Dubinskaya, E. I.,Dolmaa, G.,Klyba, L. V.
, p. 958 - 961 (2007/10/02)
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