19422-37-8

Basic information

• Product Name: 1,1,2,2-tetrakis(4-fluorophenyl)ethane
• Synonyms: 1,1,2,2-tetrakis(4-fluorophenyl)ethane
• CAS NO: 19422-37-8
• Molecular Weight: 406.423
• Mol File: 19422-37-8.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 1,1,2,2-tetrakis(4-fluorophenyl)ethane(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1,2,2-tetrakis(4-fluorophenyl)ethane(19422-37-8)
• EPA Substance Registry System: 1,1,2,2-tetrakis(4-fluorophenyl)ethane(19422-37-8)

Safety Data

• Hazardous Substances Data: 19422-37-8(Hazardous Substances Data)

Upstream product

• 457-68-1 4,4'-difluorodiphenylmethane 
• 7473-98-5 2-hydroxy-2-methylpropiophenone 
• 460-00-4 1-Bromo-4-fluorobenzene 
• 365-24-2 4,4'-difluorobenzhydryl alcohol 
• 345-92-6 4,4'-Difluorobenzophenone 
• 312-33-4 dichloro-bis-(4-fluoro-phenyl)-methane 

Downstream Products

• 61668-03-9 1,1'-(but-1-ene-4,4-diyl)bis(4-fluorobenzene) 

Relevant articles and documents

An unprecedented oxidative intermolecular homo coupling reaction between two sp3C–sp3C centers under metal-free condition

An unprecedented formation of benzylic sp3C–sp3C coupled dibenzylic products has been illustrated. The reactions have been carried out in the presence of three oxidizing reagents, i.e., diacetoxy-iodobenzene (IBDA), N-fluorobenzenesulfonimide (NFSI), and pyridine (Py) using toluene derivatives.

Use of Isopropyl Alcohol as a Reductant for Catalytic Dehydoxylative Dimerization of Benzylic Alcohols Utilizing Ti?O Bond Photohomolysis

Photohomolysis of Ti?O bonds is utilized in photocatalytic generation of titanium(III) species for dehydroxylative dimerization of benzylic alcohols under UV-light irradiation by using isopropyl alcohol (IPA) as a stoichiometric reductant. In this reaction, IPA works not as a single-electron donor as in the photo-redox catalyzed reactions but as an H-atom-donor. The reaction also proceeds under visible-light irradiation in the presence of thioglycolic acid as a ligand.

Oxidative generation of diarylcarbenium ion pools

(Figure Presented) "Cation pools" of diarylcarbenium ions have been generated by the oxidative C-H bond dissociation of diarylmethanes using anodic oxidation. "Diarylcarbenium ion pools" thus generated react with various nucleophiles, such as allylsilanes