195064-77-8

Basic information

• Product Name: Silane, [(2-methoxyphenyl)methoxy]trimethyl-
• CAS NO: 195064-77-8
• Molecular Formula: C11H18O2Si
• Molecular Weight: 210.348
• Mol File: 195064-77-8.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: Silane, [(2-methoxyphenyl)methoxy]trimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, [(2-methoxyphenyl)methoxy]trimethyl-(195064-77-8)
• EPA Substance Registry System: Silane, [(2-methoxyphenyl)methoxy]trimethyl-(195064-77-8)

Safety Data

• Hazardous Substances Data: 195064-77-8(Hazardous Substances Data)

Upstream product

• 612-16-8 (2-methoxyphenyl)methanol 
• 999-97-3 1,1,1,3,3,3-hexamethyl-disilazane 
• 993-07-7 trimethylsilan 
• 201230-82-2 carbon monoxide 
• 135-02-4 ortho-anisaldehyde 

Downstream Products

• 135-02-4 ortho-anisaldehyde 
• 35480-25-2 o-methoxybenzyl acetate 
• 64421-25-6 2-methoxybenzyl benzoate  
• 579-75-9 2-Methoxybenzoic acid 
• 612-16-8 (2-methoxyphenyl)methanol 
• 64421-24-5 2-methoxybenzyl ether 

Relevant articles and documents

Graphene oxide-bound electron-deficient tin(IV) porphyrin: a highly efficient and selective catalyst for trimethylsilylation of alcohols and phenols with hexamethyldisilazane

The catalytic activity of graphene oxide-bound tetrakis(p-aminophenyl)porphyrinatotin(IV) trifluoromethanesulfonate, [SnIV(TNH2PP)(OTf)2], in the trimethylsilylation of alcohols and phenols with hexamethyldisilazane (HMDS) is reported. The prepared catalyst was characterized using inductively coupled plasma analysis, scanning electron microscopy, transmission electron microscopy, and Fourier transform infrared and diffuse reflectance UV–visible spectroscopies. This heterogeneous catalyst was used for selective trimethylsilylation of various alcohols and phenols with HMDS in short reaction times and high yields. Also, the catalyst is of high reusability and stability, in that it was recovered several times without loss of its initial activity. The chemoselectivity of this catalytic system in the silylation of primary alcohols in the presence of secondary and tertiary alcohols and also phenols was investigated.

RuIII(OTf)SalophenCH2-NHSiO2-Fe: An efficient and magnetically recoverable catalyst for trimethylsilylation of alcohols and phenols with hexamethyldisilazane

Efficient trimethylsilylation of alcohols and phenols with hexamethyldisilazane (HMDS) catalyzed by ruthenium(III) complex of chloromethylated Salophen supported on nanomagnetic materials is reported. First, the iron nanomagnets were silica coated, functi

Highly efficient and selective trimethylsilylation of alcohols and phenols with hexamethyldisilazane catalyzed by polystyrene-bound tin(IV) porphyrin

In the present work, investigation of the catalytic activity of tetrakis(p-aminophenyl)porphyrinatotin(IV) trifluoromethanesulfonate, [Sn IV(TNH2PP)(OTf)2], supported on chloromethylated polystyrene in the trimethylsilylation of alcohols and phenols with hexamethyldisilazane is reported. The prepared catalyst was characterized by elemental analysis, FT-IR and diffuses reflectance UV-Vis spectroscopic methods. This catalyst was used for selective trimethylsilylation of different alcohols and phenols with HMDS, with short reaction times and high yields. Also the catalyst is of high reusability and stability, in that it was recovered several times without loss of its initial activity.