19514-05-7

Basic information

• Product Name: 2-(2-chlorophenoxy)-1-phenylethanone
• Synonyms: 2-(2-chlorophenoxy)-1-phenylethanone
• CAS NO: 19514-05-7
• Molecular Formula: C₁₄H₁₁ClO₂
• Molecular Weight: 246.68894
• Mol File: 19514-05-7.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-(2-chlorophenoxy)-1-phenylethanone(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(2-chlorophenoxy)-1-phenylethanone(19514-05-7)
• EPA Substance Registry System: 2-(2-chlorophenoxy)-1-phenylethanone(19514-05-7)

Safety Data

• Hazardous Substances Data: 19514-05-7(Hazardous Substances Data)

Upstream product

• 20143-53-7 2-(2-iodophenoxy)-1-phenylethan-1-one 
• 95-57-8 2-monochlorophenol 
• 70-11-1 α-bromoacetophenone 

Downstream Products

• 381730-37-6 6-(2-chloro-phenoxy)-3,5-diphenyl-3,6-dihydro-[1,3,4]oxadiazin-2-one 

Relevant articles and documents

Nickel-Catalyzed Asymmetric Addition of Aromatic Halides to Ketones: Highly Enantioselective Synthesis of Chiral 2,3-Dihydrobenzofurans Containing a Tertiary Alcohol

A highly enantioselective and straightforward synthetic procedure to chiral 3-hydroxy-2,3-dihydrobenzofurans has been developed by nickel/bisoxazoline-catalyzed intramolecular asymmetric addition of aryl halides to unactivated ketones, giving 2,3-dihydrobenzofurans with a chiral tertiary alcohol at the C-3 position in good yields and excellent enantioselectivities (up to 92percent yield and 98percent ee). The gram-scale reaction also proceeded smoothly without a loss of yield and enantioselectivity.

A simple method for the preparation of aryl phenacyl ether in micellar medium: Part I

Aryl phenacyl ethers have been prepared by the micellar catalysed reaction of phenacyl bromide with equimolar mixture of phenol(s)- triethylamine in 70% methanol(v/v) 30 °C. The ethers have been characterised on the basis of their IR, 1H and s