19742-90-6

Basic information

• Product Name: Disulfide, bis(3-bromophenyl)
• Synonyms: 1,2-bis(3-bromophenyl)disulfan;Disulfide,bis(3-bromophenyl);Di-(m-bromophenyl)-disulfid;bis-(3-bromo-phenyl)-disulfide;Bis-<3-brom-phenyl>-disulfid
• CAS NO: 19742-90-6
• Molecular Formula: C12H8Br2S2
• Molecular Weight: 376.136
• Mol File: 19742-90-6.mol
• Article Data: 13

Chemical Properties

• Boiling Point: 403.1±30.0 °C(Predicted)
• Density: 1.83±0.1 g/cm3(Predicted)
• CAS DataBase Reference: Disulfide, bis(3-bromophenyl)(CAS DataBase Reference)
• NIST Chemistry Reference: Disulfide, bis(3-bromophenyl)(19742-90-6)
• EPA Substance Registry System: Disulfide, bis(3-bromophenyl)(19742-90-6)

Safety Data

• Hazardous Substances Data: 19742-90-6(Hazardous Substances Data)

Upstream product

• 6320-01-0 3-Bromothiophenol 
• 411235-57-9 cyclopropylboronic acid 
• 925430-09-7 tricyclopropylbismuthane 
• 2905-24-0 3-Bromobenzenesulfonyl chloride 
• 3996-39-2 [(3-bromophenyl)sulfanyl]acetic acid 
• 78644-97-0 ((3-bromophenyl)thio)trimethylsilane 
• 70-11-1 α-bromoacetophenone 

Downstream Products

• 882182-71-0 2-(3-bromo-phenylsulfanyl)-5-(3-nitro-phenyl)-thiazole 
• 1451371-34-8 2-((3-bromophenyl)thio)-1,4-dioxane 
• 57992-02-6 3-bromo-benzenesulfenyl chloride 
• 79319-65-6 1-bromo-3-thiocyanatobenzene 
• 2252-45-1 1-bromo-3-[(trifluoromethyl)sulfanyl]benzene 
• 2392-86-1 3,3'-dibromodiphenyl sulfide 
• 911030-16-5 4-[S-([6-methyl-4-(2-trimethylsilanyl-ethoxycarbonylamino)-biphenyl-2-yl]-carbamic acid 2-trimethylsilanyl-ethyl ester)-N-sulfonyl-3-nitrobenzene sulfoximino]-5-methylsulfanyl-thiophene-2-carbamic acid tert-butyl ester 
• 911029-10-2 4-[S-(3-bromophenyl)-N-(3-{N,N-bismethanesulfonylamino}benzene-sulfonyl)sulfoximino]-5-methylsulfanyl-thiophene-2-carboxamidine trifluoroacetate 

Relevant articles and documents

DOCK1-INHIBITING COMPOUND AND USE THEREOF

Provided is a compound that is usable as an active ingredient of an anticancer agent. Preferably provided is a compound that has DOCK1-inhibiting activity and exerts an anticancer effect based on the activity. A compound represented by the following formula (A) or a salt thereof: wherein X represents a carbon atom or a nitrogen atom; Y represents an oxygen atom, a hydroxy group, or a hydrocarbon group; R1 and R2 are different, and each represents a hydrogen atom or a group represented by the following formula (A-1): (wherein R6 represents a pyrrolidino group or a phenyl group, and n2 is 0 or 1) ; R3 represents -CO-R7 (wherein R7 is an alkoxy group, an alkyl group, or an alkylamino group), a 1,3-oxazole group, an alkylhydroxy group, a hydrogen atom, or an oxygen atom; R4 represents a hydrogen atom, an oxygen atom, or a hydrocarbon group in which one or more hydrogen atoms may be replaced by one or more substituents; R5 represents a halogen atom, a halogenated alkyl group, or a halogenated alkylthio group; and n1 is an integer of 0 to 5; and

Metal-free chalcogenation of cycloketone oxime esters with dichalcogenides

We report the metal-free chalcogenation of cycloketone oxime esters with dichalcogenides via a radical process. Because of the metal-free condition and use of readily accessible dichalcogenides, this method is an effective and green strategy for the synthesis of chalcogen-substituted butyronitrile.

Palladium-Catalyzed Picolinamide-Directed Benzylic C(sp3)?H Chalcogenation with Diaryl Disulfides and Diphenyl Diselenide

The first palladium-catalyzed direct benzylic C(sp3)?H chalcogenation with diaryl disulfides and diphenyl diselenide has been established. The coupling reaction proceeds between the thioether radical and palladiumcycle intermediate. Picolinamide serves as an excellent directing group for the C?H activation of benzylic C(sp3)?H and can be easily removed. The current protocol exhibits a relatively broad substrate scope and high functional group compatibility. A mechanistic study indicates that palladium(IV) intermediate is probably formed during the course of the reaction. (Figure presented.).