200353-84-0

Basic information

• Product Name: 1-(4-methoxyphenyl)-1-oxopropan-2-yl acetate
• Synonyms: 1-(4-methoxyphenyl)-1-oxopropan-2-yl acetate
• CAS NO: 200353-84-0
• Molecular Weight: 222.241
• Mol File: 200353-84-0.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 1-(4-methoxyphenyl)-1-oxopropan-2-yl acetate(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(4-methoxyphenyl)-1-oxopropan-2-yl acetate(200353-84-0)
• EPA Substance Registry System: 1-(4-methoxyphenyl)-1-oxopropan-2-yl acetate(200353-84-0)

Safety Data

• Hazardous Substances Data: 200353-84-0(Hazardous Substances Data)

Upstream product

• 186581-53-3 diazomethane 
• 64-19-7 acetic acid 
• 4180-23-8 E-1-(4'-methoxyphenyl)prop-1-ene 
• 64-17-5 ethanol 
• 121-97-1 4-Methoxypropiophenone 
• 127-08-2 potassium acetate 
• 127-19-5 N,N-dimethyl acetamide 
• 3240-34-4 [bis(acetoxy)iodo]benzene 

Downstream Products

• 93379-07-8 (S)-(-)-2-hydroxy-1-(4-methoxyphenyl)-1-propan-1-one 
• 143191-63-3 (R)-(+)-2-hydroxy-1-(4-methoxyphenyl)-1-propan-1-one 
• 15482-28-7 2-hydroxy-1-(4-methoxyphenyl)-propan-1-one 

Relevant articles and documents

PIDA/Bu4NBr/KOH-oxidized direct α-acetoxylation of sp 3 C-H bonds adjacent to carbonyl

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Synthesis of α-acetoxy and formyloxy ketones by thallium(III) promoted α-oxidation

Treatment of ketones with thallium(III) triflate in amide solvents at 60°C for 30 min followed by addition of small amounts of H2O cleanly provided the corresponding α-acyloxy ketones.

A facile synthesis of secondary α-alkoxy or α-acetoxy aromatic ketones

The treatment of HNIB with aromatic ketones and subsequent solvolysis using alcohol or acetic acid in one-pot system makes it possible to give corresponding secondary α-alkoxy or α-acetoxy ketones in high yields.