204653-23-6

Basic information

• Product Name: dichloroplatinum(II)((R)-p-tolyl-BINAP
• CAS NO: 204653-23-6
• Molecular Weight: 944.779
• Mol File: 204653-23-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: dichloroplatinum(II)((R)-p-tolyl-BINAP(CAS DataBase Reference)
• NIST Chemistry Reference: dichloroplatinum(II)((R)-p-tolyl-BINAP(204653-23-6)
• EPA Substance Registry System: dichloroplatinum(II)((R)-p-tolyl-BINAP(204653-23-6)

Safety Data

• Hazardous Substances Data: 204653-23-6(Hazardous Substances Data)

Upstream product

• 153305-67-0 (+)-(R)-2,2'bis(di-para-tolylphosphanyl)-1,1'binaphthyl 
• 36389-82-9 dichlorobis(tetrahydrothiophene)platinum(II) 
• 12080-32-9 dichloro(1,5-cyclooctadiene)platinum(ll) 
• 153305-67-0 (R)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl 

Downstream Products

• 204719-49-3 Pt(R-Tol-Binap)(trans-stilbene)*THF 

Relevant articles and documents

PGSE diffusion NMR studies on mononuclear and dinuclear cationic platinum salts of (S)-MeO-Biphep and (R)-p-tolyl-BINAP

PGSE diffusion NMR studies on a series of mononuclear and dinuclear cationic platinum salts derived from (S)-MeO-Biphep and (R)-p-tolyl-BINAP are reported. The data show that (a) one can readily distinguish between mononuclear and dinuclear cations (b) the amount of ion pairing can be estimated qualitatively and (c) the charge delocalization rather than the amount of formal charge per metal cation is important for the position of the anion. The solid-state structure of the chloro-bridged salt, [Pt(μ-Cl){(S)-MeO-Biphep}]2(CF3SO3)2, is reported.