204719-49-3

Basic information

• Product Name: Pt(R-Tol-Binap)(trans-stilbene)*THF
• Synonyms: Pt(R-Tol-Binap)(trans-stilbene)*THF
• CAS NO: 204719-49-3
• Molecular Weight: 1126.23
• Mol File: 204719-49-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Pt(R-Tol-Binap)(trans-stilbene)*THF(CAS DataBase Reference)
• NIST Chemistry Reference: Pt(R-Tol-Binap)(trans-stilbene)*THF(204719-49-3)
• EPA Substance Registry System: Pt(R-Tol-Binap)(trans-stilbene)*THF(204719-49-3)

Safety Data

• Hazardous Substances Data: 204719-49-3(Hazardous Substances Data)

Upstream product

• 153305-67-0 (R)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl 
• 103-30-0 (E)-1,2-diphenyl-ethene 
• 204653-23-6 Pt(R-Tol-Binap)Cl₂ 

Relevant articles and documents

Platinum(0) complexes of chiral diphosphines: Enantioface-selective binding of trans-stilbene

The zerovalent complexes Pt(diphos)(trans-stilbene) (diphos = dppe, dppf, (S,S)-Chiraphos, R-Tol-Binap, (R,R)-Me-Duphos, (S,S)-Diop) were prepared by reduction of the corresponding Pt(diphos)Cl2 compounds. NMR and crystal structure data show that the trans-stilbene complexes with chiral diphosphines exist as a mixture of diastereomers differing in their binding of the enantiofaces of the prochiral olefin; for R-Tol-Binap, they can be separated by recrystallization. The complexes Pt((R,R)-Me-Duphos)Cl2 and Pt(diphos)(trans-stilbene) (diphos = dppf, (S,S)-Chiraphos, R-Tol-Binap, (S,S)-Diop) were structurally characterized by X-ray crystallography.