20615-47-8

Basic information

• Product Name: 4'-METHOXY-3-(4-METHOXYPHENYL)PROPIOPHENONE
• Synonyms: 4'-METHOXY-3-(4-METHOXYPHENYL)PROPIOPHENONE
• CAS NO: 20615-47-8
• Molecular Formula: C₁₇H₁₈O₃
• Molecular Weight: 270.32
• Mol File: 20615-47-8.mol
• Article Data: 30

Chemical Properties

• Melting Point: 42-43 °C
• Boiling Point: 427.2°C at 760 mmHg
• Flash Point: 203.9°C
• Appearance: /
• Density: 1.098g/cm³
• Vapor Pressure: 1.67E-07mmHg at 25°C
• Refractive Index: 1.552
• CAS DataBase Reference: 4'-METHOXY-3-(4-METHOXYPHENYL)PROPIOPHENONE(CAS DataBase Reference)
• NIST Chemistry Reference: 4'-METHOXY-3-(4-METHOXYPHENYL)PROPIOPHENONE(20615-47-8)
• EPA Substance Registry System: 4'-METHOXY-3-(4-METHOXYPHENYL)PROPIOPHENONE(20615-47-8)

Safety Data

• Hazardous Substances Data: 20615-47-8(Hazardous Substances Data)

Usage

InChI:InChI=1/C17H18O3/c1-19-15-8-3-13(4-9-15)5-12-17(18)14-6-10-16(20-2)11-7-14/h3-4,6-11H,5,12H2,1-2H3

Upstream product

• 41564-67-4 (E)-1,3-bis(4-methoxyphenyl)-2-propene-1-one 
• 121198-57-0 1,1,1-triphenyl-2-aza-1λ⁵-phosphabuta-1,3-diene 
• 2393-23-9 4-methoxy-benzylamine 
• 100-06-1 1-(4-methoxyphenyl)ethanone 
• 637-69-4 4-Methoxystyrene 
• 100-09-4 4-methoxybenzoic acid 
• 7448-86-4 1-(4-methoxyphenyl)prop-2-en-1-one 
• 5720-07-0 4-methoxyphenylboronic acid 
• 15973-65-6 1-(4-methoxyphenyl)cyclopropan-1-ol 
• 171364-79-7 2-(4-methoxyphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 696-62-8 para-iodoanisole 
• 107-18-6 allyl alcohol 
• 1515-81-7 1-methoxy-4-(methoxymethyl)benzene 
• 105-13-5 4-Methoxybenzyl alcohol 

Downstream Products

• 106511-72-2 2-Bromo-1,3-bis-(4-methoxy-phenyl)-propan-1-one 
• 1344666-94-9 4'-methoxy-2-(4-methoxybenzyl)-5-methylbiphenyl 
• 1344666-92-7 2-(4-methoxybenzyl)-1-(4-methoxyphenyl)-5-methylhex-4-en-1-one 
• 34414-53-4 (E)-1-methoxy-4-(3-(4-methoxyphenyl)allyl)benzene 
• 1446018-07-0 N,5-bis(4-methoxybenzyl)-4-(4-methoxyphenyl)thiazol-2-amine 
• 93724-39-1 2-amino-1,3-bis-(4-methoxy-phenyl)-propan-1-ol 
• 106511-77-7 N-[5-(4-Methoxy-benzyl)-4-(4-methoxy-phenyl)-thiazol-2-yl]-acetamide 
• 106511-79-9 5-(4-Methoxy-benzyl)-4-(4-methoxy-phenyl)-2-methylsulfanyl-thiazole 
• 106511-78-8 5-(4-Methoxy-benzyl)-4-(4-methoxy-phenyl)-thiazole-2-thiol 
• 106511-67-5 5-(4-methoxybenzyl)-4-(4-methoxyphenyl)thiazol-2-amine 
• 226075-03-2 3-cyano-5-(4-methoxybenzyl)-6-(4-methoxyphenyl)-4-methylthio-2H-pyran-2-one 
• 107944-03-6 1,3-bis-(4-methoxy-phenyl)-propane-1,2-dione-2-oxime 

Relevant articles and documents

Reaction of N,N-dimethylacrylamide/trifluoromethanesulfonic anhydride complex with electron-rich aromatic compounds

The reaction of N,N-dimethylacrylamide/trifluoromethanesulfonic anhydride complex with electron-rich aromatic compounds affords after hydrolysis the corresponding indanones and 1,3-diarylpropanones.

Designed pincer ligand supported Co(ii)-based catalysts for dehydrogenative activation of alcohols: Studies onN-alkylation of amines, α-alkylation of ketones and synthesis of quinolines

Base-metal catalystsCo1,Co2andCo3were synthesized from designed pincer ligandsL1,L2andL3having NNN donor atoms respectively.Co1,Co2andCo3were characterized by IR, UV-Vis. and ESI-MS spectroscopic studies. Single crystal X-ray diffraction studies were investigated to authenticate the molecular structures ofCo1andCo3. CatalystsCo1,Co2andCo3were utilized to study the dehydrogenative activation of alcohols forN-alkylation of amines, α-alkylation of ketones and synthesis of quinolines. Under optimized reaction conditions, a broad range of substrates including alcohols, anilines and ketones were exploited. A series of control experiments forN-alkylation of amines, α-alkylation of ketones and synthesis of quinolines were examined to understand the reaction pathway. ESI-MS spectral studies were investigated to characterize cobalt-alkoxide and cobalt-hydride intermediates. Reduction of styrene by evolved hydrogen gas during the reaction was investigated to authenticate the dehydrogenative nature of the catalysts. Probable reaction pathways were proposed forN-alkylation of amines, α-alkylation of ketones and synthesis of quinolines on the basis of control experiments and detection of reaction intermediates.

Preparation method of novel aromatic ketone compound

The invention discloses a preparation method of a novel aromatic ketone compound. According to the preparation method, an aromatic carboxylic acid compound and an aromatic olefin compound are used asreaction raw materials, triphenylphosphine is taken as a deoxidizing reagent, Methylenene blue is taken as a photocatalyst, stirring and reacting are carried out at room temperature in an N,N-dimethylacetamide solvent under the irradiation of a white light lamp in a nitrogen atmosphere and under the condition of taking 2,4,6-trimethylpyridine as an alkali, thereby obtaining a target product, namely the aromatic ketone compound. The method has the advantages of mild reaction conditions, simplicity in operation, low cost, convenience in purification, environmental friendliness and the like.