20643-65-6

Basic information

• Product Name: 1(3H)-Isobenzofuranone, 3-(4-nitrophenyl)-
• CAS NO: 20643-65-6
• Molecular Formula: C14H9NO4
• Molecular Weight: 255.23
• Mol File: 20643-65-6.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 1(3H)-Isobenzofuranone, 3-(4-nitrophenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1(3H)-Isobenzofuranone, 3-(4-nitrophenyl)-(20643-65-6)
• EPA Substance Registry System: 1(3H)-Isobenzofuranone, 3-(4-nitrophenyl)-(20643-65-6)

Safety Data

• Hazardous Substances Data: 20643-65-6(Hazardous Substances Data)

Upstream product

• 98-95-3 nitrobenzene 
• 88-95-9 Phthaloyl dichloride 
• 555-16-8 4-nitrobenzaldehdye 
• 88-65-3 2-bromobenzoic-acid 
• 1049009-41-7 2-(4-nitrobenzoyl)benzaldehyde 

Downstream Products

• 612-20-4 2-(hydroxymethyl)benzoic acid 
• 617-94-7 1-methyl-1-phenylethyl alcohol 
• 98-86-2 acetophenone 

Relevant articles and documents

Lewis acid-assisted dirhodium(II)-catalyzed ketone hydroacylation

The combination of a Rh(II) salt and a Lewisacid, Sc(OTf)3, as a highly active and robust cooperative catalyst system for ketone hydroacylation was developed. The catalyst system showed high turnover numbers (up to ca. 400) even under air, whereas the corresponding Rh(I)/Sc(OTf)3 system did not work well. The application of the Rh(II)/Sc system was also extended to hydroacylation of olefins and an enantioselective reaction.

Synthesis and characterization of benzannelated thienyl oligomers

An array of 1,3-diarylbenzo[c]thiophenes have been synthesized by the ring-opening of lactones followed by thionation using Lawesson's reagent with concurrent intramolecular cyclization. Photophysical studies of the various benzo[c]thiophene analogues are presented. The results of a cyclic voltammetric investigation of the benzo[c]thiophenes are also reported.