207456-08-4

Basic information

• Product Name: Pt(I)(Me)(diacetyl bis(di-i-propylphenylimine))
• CAS NO: 207456-08-4
• Molecular Weight: 741.658
• Mol File: 207456-08-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Pt(I)(Me)(diacetyl bis(di-i-propylphenylimine))(CAS DataBase Reference)
• NIST Chemistry Reference: Pt(I)(Me)(diacetyl bis(di-i-propylphenylimine))(207456-08-4)
• EPA Substance Registry System: Pt(I)(Me)(diacetyl bis(di-i-propylphenylimine))(207456-08-4)

Safety Data

• Hazardous Substances Data: 207456-08-4(Hazardous Substances Data)

Upstream product

• 14104-20-2 silver tetrafluoroborate 
• 199284-91-8 [PtCl(Me)(diacetyl bis(2,6-diisopropylphenylimine))] 
• 7681-11-0 potassium iodide 

Downstream Products

• 207456-01-7 [PtMe(diacetyl bis(di-i-propylphenylimine))(η(2)-CH2=CHCHO)]BF4 

Relevant articles and documents

The first class of square-planar platinum(II) complexes containing electron-poor alkenes. Rare insertion of an alkene into a Pt-alkyl bond

The first class of square-planar Pt(II) complexes bearing electron-poor alkenes, i.e., [PtMe-N,N-chelate)(η2-CH2=CHCOR)]BF4 (R = H, NMe2, Me, OMe), is described. By using N,N ligands with suitable steric properties, it was possible to inhibit olefin dynamic processes in solution, thus allowing a thorough characterization of the complexes. Insertion of methyl acrylate into the Pt-Me bond provides a rare example of migratory insertion of an alkene into a Pt-alkyl bond.