209667-83-4

Basic information

• Product Name: 4-Phenyl-pyridine-2-carboximidic acid methyl ester
• Synonyms: 4-Phenyl-pyridine-2-carboximidic acid methyl ester
• CAS NO: 209667-83-4
• Molecular Weight: 212.251
• Mol File: 209667-83-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4-Phenyl-pyridine-2-carboximidic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Phenyl-pyridine-2-carboximidic acid methyl ester(209667-83-4)
• EPA Substance Registry System: 4-Phenyl-pyridine-2-carboximidic acid methyl ester(209667-83-4)

Safety Data

• Hazardous Substances Data: 209667-83-4(Hazardous Substances Data)

Upstream product

• 1131-61-9 4-Phenylpyridine 1-oxide 
• 67-56-1 methanol 
• 18714-16-4 4-phenyl-pyridine-2-carbonitrile 

Relevant articles and documents

Novel chiral oxazoline ligands for potential charge-transfer effects in the Rh(I)-catalysed enantioselective hydrosilylation

Novel 2-(4,4′-bipyridin-2-yl)oxazolines, bearing a chiral oxazoline moiety, were synthesised starting from 4,4′-bipyridine and selectively monomethylated in the N′-position. After coordination to rhodium these electron-poor ligands are supposed to exhibit charge-transfer effects with electron-donating substrates in the Rh(I)-catalysed enantioselective hydrosilylation (see next publication). Similar effects were expected from 4,4′-bipyridine- and pyrazine-bisoxazolines after complexation with rhodium. For comparison 2-(4-phenylpyridin-2-yl)oxazoline ligands were synthesised. Rh(I)-complexes of selected ligands were prepared and characterised, including an X-ray structure analysis.