209974-60-7

Basic information

• Product Name: 1-[(2-formylamino)phenyl]pyrrole
• Synonyms: 1-[(2-formylamino)phenyl]pyrrole
• CAS NO: 209974-60-7
• Molecular Weight: 186.213
• Mol File: 209974-60-7.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: 1-[(2-formylamino)phenyl]pyrrole(CAS DataBase Reference)
• NIST Chemistry Reference: 1-[(2-formylamino)phenyl]pyrrole(209974-60-7)
• EPA Substance Registry System: 1-[(2-formylamino)phenyl]pyrrole(209974-60-7)

Safety Data

• Hazardous Substances Data: 209974-60-7(Hazardous Substances Data)

Upstream product

• 6025-60-1 2-(1H-pyrrol-1-yl)aniline 
• 109-94-4 formic acid ethyl ester 
• 615-43-0 2-iodophenylamine 
• 2258-42-6 formyl acetic anhydride 

Downstream Products

• 350829-07-1 1-[2-isocyanophenyl]-1H-pyrrole 
• 37046-17-6 pyrrolo[1,2-a]quinoxaline-4(5H)-thione 
• 33265-71-3 1-(2-isocyanophenyl)-1H-pyrrole 
• 234-95-7 pyrrolo[1,2-a]quinoxaline 
• 79323-12-9 4-benzoylpyrrolo<1,2-a>quinoxaline 

Relevant articles and documents

Synthesis of pyrrolo[1,2-a]quinoxaline derivatives by lewis acid-catalyzed reactions of 1-(2-isocyanophenyl)pyrroles

1-(2-Isocyanophenyl)pyrroles have been prepared. They react in moderate to good isolated yields with aldehydes (or ketones), oxiranes, and acetals in the presence of catalytic amounts of diethyl ether-boron trifluoride to give pyrrolo [1,2-a]quinoxalines carrying an oxyalkyl substituent, such as α-hydroxyalkyl, β-hydroxyalkyl, or α-alkoxyalkyl, at the 4-position.

Catalyst-free synthesis of phenanthridinesviaelectrochemical coupling of 2-isocyanobiphenyls and amines

Catalyst free synthesis of 6-aryl phenanthridines and amides through an electrochemical reaction is reported in this study. The coupling reaction proceeds by the cathodic reduction ofin situformed diazonium ions, which are formed from anilines and an alkyl nitrite. The generated aryl radical diazonium ions coupled from isocyanides furnished the desired products in good yields. This cascade reaction was conducted in an undivided cell equipped with an RVC as the anode and Pt as the cathode usingnBu4NBF4as the electrolyte at room temperature. A series of detailed mechanistic studies have also been performed, including a radical clock experiment and cyclic voltammetry analysis.

6π-Electrocyclization in water: microwave-assisted synthesis of polyheterocyclic-fused quinoline-2-thiones

Microwave-assisted synthesis of polyheterocyclic-fused quinoline-2-thiones through the annulation of ortho-heteroaryl anilines and CS2 was realized in water without using any catalysts and additives. The desired products were obtained in high yields throu

AgI-Promoted Difluoromethylation of Isocyanides To Give Difluoromethylated Phenanthridines

An AgI-mediated ethoxycarbonyldifluoromethylation of isocyanides has been developed. This radical cascade reaction involves the addition of difluoromethylene radical to the isocyanide functionality, and subsequent homolytic aromatic substitution to give difluoromethylated phenanthridines with a good functional-group tolerance.