215958-46-6Relevant articles and documents
A Titanium Dioxide Supported Gold Nanoparticle Catalyst for the Selective N-Formylation of Functionalized Amines with Carbon Dioxide and Hydrogen
Mitsudome, Takato,Urayama, Teppei,Fujita, Shu,Maeno, Zen,Mizugaki, Tomoo,Jitsukawa, Koichiro,Kaneda, Kiyotomi
, p. 3632 - 3636 (2017)
A TiO2-supported, gold nanoparticle catalyst was found to allow the N-formylation of various amines, including normally unreactive anilines, by using CO2 as the carbonyl source under a H2 atmosphere. A series of reducible functional groups, such as olefins, halogens, carbonyls, carbamates, and cyano moieties, were completely retained during the formylation, which proved the highly selective nature of the formylation reaction. The catalyst was also found to be reusable without any loss of activity or selectivity.
Copper-Catalyzed Synthesis and Applications of Yndiamides
Mansfield, Steven J.,Christensen, Kirsten E.,Thompson, Amber L.,Ma, Kai,Jones, Michael W.,Mekareeya, Aroonroj,Anderson, Edward A.
supporting information, p. 14428 - 14432 (2017/10/20)
The first synthetic route to yndiamides, a novel class of double aza-substituted alkyne, has been established by the copper(I)-catalyzed cross-coupling of 1,1-dibromoenamides with nitrogen nucleophiles. The utility of these compounds is demonstrated in a
