217096-53-2Relevant articles and documents
The syntheses of pyridine-functionalyzed methylidynetricobalt nona-carbonyl clusters, their X-ray analyses, and its coordination to Pd(II)1
Onaka, Satoru,Katsukawa, Yoshitaka,Shiotsuka, Michito
, p. 113 - 119 (1998)
Two kinds of methylidynetricobalt nonacarbonyls with a pyridine functional group as an apical substituent have been synthesized from trichloromethylpyridine derivatives. The structures of two new clusters have been determined by single crystal X-ray analysis. EH-MO calculations have shown that the atomic charge on the N atom in NC5H4-3-CCo3(CO)9 is close to that of β-picoline. This cluster can coordinate to Pd(II) and trans-PdCl2{NC5H4-3-CCo3(CO) 9}2 with a nanometer dimension has been synthesized as a precursor of molecular dot.