2177-34-6 Usage
Description
1-Cyclohexyl-2-propen-1-one, also known as Cyclohexyl Vinyl Ketone, is an organic compound with the molecular formula C9H12O. It is a colorless to pale yellow liquid with a distinctive odor. 1-cyclohexyl-2-propen-1-one is characterized by its cyclohexyl group attached to a vinyl ketone moiety, which provides it with unique chemical properties and reactivity.
Uses
1. Used in Chemical Synthesis:
1-Cyclohexyl-2-propen-1-one is used as a reagent for the synthesis of α,β-unsaturated carbonyl compounds. These compounds are important in the production of various chemicals and pharmaceuticals due to their versatile reactivity and functional group compatibility.
2. Used in Pharmaceutical Industry:
In the pharmaceutical industry, 1-cyclohexyl-2-propen-1-one is used as a key intermediate in the synthesis of drugs with diverse therapeutic applications. Its ability to form α,β-unsaturated carbonyl compounds allows for the creation of complex molecular structures with potential medicinal properties.
3. Used in Flavor and Fragrance Industry:
1-Cyclohexyl-2-propen-1-one may also find applications in the flavor and fragrance industry, where it can be used to create unique scents and flavors for various products. Its distinct chemical structure can contribute to the development of novel aromas and tastes.
4. Used in Material Science:
In material science, 1-cyclohexyl-2-propen-1-one can be utilized in the development of advanced materials, such as polymers and coatings, due to its reactive nature and ability to form α,β-unsaturated carbonyl compounds. These materials can have improved properties, such as enhanced durability, stability, or specific functional characteristics.
5. Used in Research and Development:
1-Cyclohexyl-2-propen-1-one is a valuable compound for research and development purposes, particularly in the fields of organic chemistry, medicinal chemistry, and materials science. Its unique structure and reactivity make it an interesting subject for studying new reactions, mechanisms, and potential applications.
Check Digit Verification of cas no
The CAS Registry Mumber 2177-34-6 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 2,1,7 and 7 respectively; the second part has 2 digits, 3 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 2177-34:
(6*2)+(5*1)+(4*7)+(3*7)+(2*3)+(1*4)=76
76 % 10 = 6
So 2177-34-6 is a valid CAS Registry Number.
InChI:InChI=1/C9H14O/c1-2-9(10)8-6-4-3-5-7-8/h2,8H,1,3-7H2
2177-34-6Relevant articles and documents
Palladium-mediated ring opening of hydroxycyclopropanes
Park, Soon-Bong,Cha, Jin Kun
, p. 147 - 149 (2000)
(matrix presented) The palladium-mediated ring opening of substituted cyclopropanols has been found to take place predominantly at the less substituted C-C bond. Thus, sequential application of the titanium-mediated cyclopropanation of esters and the palladium-mediated ring opening of the resulting cyclopropanols provides a convenient method for functionalizing monosubstituted olefins.
Studies Targeting Ryanodol Result in an Annulation Reaction for the Synthesis of a Variety of Fused Carbocycles
Karmakar, Rajdip,Rheingold, Arnold L.,Micalizio, Glenn C.
supporting information, p. 6126 - 6129 (2019/08/26)
An annulation reaction is described to access a range of polycyclic and highly oxygenated carbocycles. First developed in an approach to the synthesis of ryanodol, metallacycle-mediated annulative diketone-alkyne coupling defines a framework for realization of new retrosynthetic relationships for complex molecule synthesis. In addition to demonstrating this reaction in the context of forging distinct carbocyclic systems, including those featuring a seven-membered ring, the choice of quenching reagent leads to unique reaction outcomes.
Indium(III)-Catalyzed Hydration and Hydroalkoxylation of α,β-Unsaturated Ketones in Aqueous Media
Yun, Jin-Jin,Zhi, Man-Ling,Shi, Wen-Xiao,Chu, Xue-Qiang,Shen, Zhi-Liang,Loh, Teck-Peng
supporting information, p. 2632 - 2637 (2018/05/30)
The hydration of α,β-unsaturated ketones with water proceeded efficiently in the presence of In(OTf)3 (20 mol%) in aqueous media to afford synthetically versatile β-hydroxyketones in moderate to good yields with good functional group compatibility. The method also can be extended to the hydroalkoxylation of α,β-unsaturated ketones with various alcohols for the efficient synthesis of β-alkoxyketones as well as tetrahydrofuran derivatives. (Figure presented.).
