21864-90-4Relevant articles and documents
Palladium-Catalyzed Synthesis of Aryl Nitriles: Using α-Iminonitrile as Cyano Source for Aryl Halide Cyanations
Shi, Yu-Long,Yuan, Qing,Chen, Zhen-Bang,Zhang, Fang-Ling,Liu, Kui,Zhu, Yong-Ming
, p. 359 - 363 (2017/11/15)
An efficient and ligand-free palladium-catalyzed exchange reaction to synthesize aryl nitriles by using α-iminonitrile as a starting reagent has been developed. This methodology provides an optional method for the synthesis of aryl nitriles with moderate to good yields. At the same time, this approach is adaptable for many substrates.
Cyano-O-silylhydroxylamines as Nitrone Blocking Groups
Padwa, Albert,Koehler, Konrad F.
, p. 789 - 790 (2007/10/02)
Addition of trimethylsilyl cyanide to N-alkyl-C-phenylnitrones affords cyano-O-silylhydroxylamines; reaction of these species with silver fluoride regenerates the nitrone in quantitative yield thereby providing a useful nitrone blocking group.
Une nouvelle methode de transformation des aldehydes aromatiques en α-iminonitriles Ar-C(CN)=N-R
Pochat, Francis
, p. 955 - 956 (2007/10/02)
The reaction with amines of bromoderivates Ar-CBr(SEt)-CN, easily obtained in high yields from aldehydes, provides a convinient route to C-aryl N-alkyl (or aryl) α-iminonitriles.