221004-69-9

Basic information

• Product Name: (2S,3S)-2-Dibenzylamino-3-hydroxy-4-methyl-pentanoic acid {(S)-1-[(R)-2-(4-fluoro-3-nitro-phenyl)-2-hydroxy-ethylcarbamoyl]-3-methyl-butyl}-amide
• Synonyms: (2S,3S)-2-Dibenzylamino-3-hydroxy-4-methyl-pentanoic acid {(S)-1-[(R)-2-(4-fluoro-3-nitro-phenyl)-2-hydroxy-ethylcarbamoyl]-3-methyl-butyl}-amide
• CAS NO: 221004-69-9
• Molecular Weight: 622.737
• Mol File: 221004-69-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (2S,3S)-2-Dibenzylamino-3-hydroxy-4-methyl-pentanoic acid {(S)-1-[(R)-2-(4-fluoro-3-nitro-phenyl)-2-hydroxy-ethylcarbamoyl]-3-methyl-butyl}-amide(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,3S)-2-Dibenzylamino-3-hydroxy-4-methyl-pentanoic acid {(S)-1-[(R)-2-(4-fluoro-3-nitro-phenyl)-2-hydroxy-ethylcarbamoyl]-3-methyl-butyl}-amide(221004-69-9)
• EPA Substance Registry System: (2S,3S)-2-Dibenzylamino-3-hydroxy-4-methyl-pentanoic acid {(S)-1-[(R)-2-(4-fluoro-3-nitro-phenyl)-2-hydroxy-ethylcarbamoyl]-3-methyl-butyl}-amide(221004-69-9)

Safety Data

• Hazardous Substances Data: 221004-69-9(Hazardous Substances Data)

Upstream product

• 87421-21-4 (2S,3S)-3-hydroxyleucine methyl ester 
• 10148-70-6 (2S,3S)-3-hydroxyleucine 
• 202478-35-1 (2S,3S)-N,N-dibenzyl hydroxyleucine 
• 221004-71-3 (S)-2-Amino-4-methyl-pentanoic acid [(R)-2-(4-fluoro-3-nitro-phenyl)-2-hydroxy-ethyl]-amide 
• 221004-70-2 (2S,3S)-2-Dibenzylamino-3-hydroxy-4-methyl-pentanoic acid pentafluorophenyl ester 

Downstream Products

• 107462-36-2 sanjoinine G₁ 
• 221004-76-8 O-Ac-sanjoinine G₁ 
• 221004-75-7 Acetic acid (3S,4S,7S,11R)-4-dibenzylamino-7-isobutyl-3-isopropyl-5,8-dioxo-2-oxa-6,9-diaza-bicyclo[10.2.2]hexadeca-1⁽¹⁵⁾,12⁽¹⁶⁾,13-trien-11-yl ester 
• 221004-74-6 Acetic acid (3S,4S,7S,11R)-4-dibenzylamino-7-isobutyl-3-isopropyl-14-nitro-5,8-dioxo-2-oxa-6,9-diaza-bicyclo[10.2.2]hexadeca-1⁽¹⁵⁾,12⁽¹⁶⁾,13-trien-11-yl ester 
• 221004-73-5 (3S,4S,7S,11R)-4-Dibenzylamino-11-hydroxy-7-isobutyl-3-isopropyl-14-nitro-2-oxa-6,9-diaza-bicyclo[10.2.2]hexadeca-1⁽¹⁵⁾,12⁽¹⁶⁾,13-triene-5,8-dione 

Relevant articles and documents

A convergent approach to cyclopeptide alkaloids: Total synthesis of sanjoinine G1

A general strategy for the synthesis of cyclopeptide alkaloids containing an endocyclic aryl-alkyl ether bond has been developed featuring a key intramolecular SNAr reaction. The importance of the N-terminal protective group in the realization