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223137-67-5

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223137-67-5 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 223137-67-5 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 2,2,3,1,3 and 7 respectively; the second part has 2 digits, 6 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 223137-67:
(8*2)+(7*2)+(6*3)+(5*1)+(4*3)+(3*7)+(2*6)+(1*7)=105
105 % 10 = 5
So 223137-67-5 is a valid CAS Registry Number.

223137-67-5Relevant articles and documents

1,1'-Spirobiindane-7,7'-diol: A novel, C2-symmetric chiral ligand

Birman, Vladimir B.,Rheingold, Arnold L.,Lam, Kin-Chung

, p. 125 - 131 (1999)

A novel, C2-symmetric chiral diol (16) was prepared in six steps from m-anisaldehyde and resolved via its bis-L-menthoxycarboxylate.

Chiral oligomers of spiro-salencobalt(III)X for catalytic asymmetric cycloaddition of epoxides with CO2

Zhu, Zhouhe,Zhang, Yuqian,Wang, Kai,Fu, Xiying,Chen, Fengjuan,Jing, Huanwang

, p. 50 - 53 (2016/05/10)

Several new chiral oligomers of spiro-salenCo(III)X (spiro = 1.1′-spirobiindane-7.7′-diol) complexes have been designed, synthesized, and characterized by nuclear magnetic resonance (NMR), infrared (IR), and elemental analyses, in which, the chiral spiro moieties are first introduced into a scaffold of chiral salenCo catalysts. They were used to catalyze the asymmetric cycloaddition of epoxides with carbon dioxide. Under very mild reaction conditions, a kinetic resolution of racemic epoxides with CO2 was smoothly initiated by these chiral oligomer catalysts with good enantioselectivities, which can be attributed to the match effect between chiral backbones of salen and spiro. High stability and easy recyclability are their major advantages.

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