2234-26-6

Basic information

• Product Name: 2-NORBORNANECARBONITRILE
• Synonyms: norbornane-2-carbonitrile;2-NORBORNANECARBONITRILE, 98%, MIXTURE O F ENDO AND EXO;2-norbornanecarbonitrile, mixture of endo and exo;2-Norbornanecarbonitrile, GC 96%;2-Norbornanecarbonitrile, mixture of endo andexo,98%;2-Norbornanecarbonitrile,96%,mixture of endoand exo;TIMTEC-BB SBB008462;2-NORBORNANECARBONITRILE
• CAS NO: 2234-26-6
• Molecular Formula: C₈H₁₁N
• Molecular Weight: 121.18
• EINECS: 218-782-9
• Product Categories: C8 to C9;Cyanides/Nitriles;Nitrogen Compounds;C8 to C9;Building Blocks;Chemical Synthesis;Nitrogen Compounds;Organic Building Blocks
• Mol File: 2234-26-6.mol
• Article Data: 14

Chemical Properties

• Melting Point: 43-45 °C(lit.)
• Boiling Point: 73-75 °C10 mm Hg(lit.)
• Flash Point: 174 °F
• Appearance: white to beige-brown adhering crystalline solid
• Density: 0.8967 (rough estimate)
• Vapor Pressure: 0.49mmHg at 25°C
• Refractive Index: 1.4525 (estimate)
• CAS DataBase Reference: 2-NORBORNANECARBONITRILE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-NORBORNANECARBONITRILE(2234-26-6)
• EPA Substance Registry System: 2-NORBORNANECARBONITRILE(2234-26-6)

Safety Data

• Hazard Codes: F,Xn
• Statements: 11-20/21/22-36/37/38
• Safety Statements: 16-26-27-36/37/39
• RIDADR: UN 1325 4.1/PG 2
• WGK Germany: 3
• RTECS: RB6960000
• HazardClass: 4.1
• PackingGroup: III
• Hazardous Substances Data: 2234-26-6(Hazardous Substances Data)

Usage

Description

2-NORBORNANECARBONITRILE, also known as Bicyclo[2.2.1]heptane-2-carbonitrile, is a white to beige-brown adhering crystalline solid. It is a chemical compound with a unique bicyclic structure that makes it a valuable reagent in the synthesis of various organic compounds.

Uses

Used in Chemical Synthesis:
2-NORBORNANECARBONITRILE is used as a reagent for the preparation of cyanoboranes and polynorbornenes. Its unique bicyclic structure and carbonitrile functional group make it a versatile building block in the synthesis of complex organic molecules.
Used in Polymer Industry:
In the polymer industry, 2-NORBORNANECARBONITRILE is used as a monomer for the production of polynorbornenes. These polymers have a wide range of applications, including as high-performance materials in various industries such as automotive, aerospace, and electronics.
Used in Pharmaceutical Industry:
2-NORBORNANECARBONITRILE can also be used as a starting material for the synthesis of pharmaceutical compounds. Its unique structure and reactivity make it a promising candidate for the development of new drugs and drug delivery systems.
Overall, 2-NORBORNANECARBONITRILE is a versatile chemical compound with a wide range of applications in various industries, including chemical synthesis, polymer production, and pharmaceutical development. Its unique properties and reactivity make it a valuable asset in the development of new materials and products.

InChI:InChI=1/C8H11N/c9-5-8-4-6-1-2-7(8)3-6/h6-8H,1-4H2/t6-,7+,8-/m1/s1

Upstream product

• 29342-65-2 2-bromonorbornane 
• 143-33-9 sodium cyanide 
• 934-28-1 bicyclo(2.2.1)heptane-2-endo-carboxylic acid 
• 7677-24-9 trimethylsilyl cyanide 
• 585-71-7 (1-bromoethyl)benzne 
• 2534-77-2 exo-2-bromonorbornane 
• 80605-69-2 endo-2-Norbornylisonitril 
• 76649-94-0 endo-bicyclo[2.2.1]heptane-2-carboxamide 
• 34560-28-6 2-vinylbenzonitrile 
• 498-66-8 norbornene 
• 934-29-2 acide bicyclo<2.2.1>heptane carboxylique-2 exo 
• 80605-69-2 exo-2-Norbornylisonitril 
• 768-15-0 exo-bicyclo[2.2.1]heptane-2-carboxamide 
• 498-66-8 norborn-2-ene 

Downstream Products

• 76649-94-0 endo-bicyclo[2.2.1]heptane-2-carboxamide 
• 1039766-35-2 C₁₉H₂₈N₂ 
• 934-28-1 norbornane-2-carboxylic acid 
• 279-23-2 norbornene 
• 4040-59-9 2-Aminomethylbicyclo<2.2.1>heptane hydrochloride 

Relevant articles and documents

Biomolecule-derived supported cobalt nanoparticles for hydrogenation of industrial olefins, natural oils and more in water

Catalytic hydrogenation of olefins using noble metal catalysts or pyrophoric RANEY nickel is of high importance in the chemical industry. From the point of view of green and sustainable chemistry, design and development of Earth-abundant, less toxic, and more environmentally friendly catalysts are highly desirable. Herein, we report the convenient preparation of active cobalt catalysts and their application in hydrogenations of a wide range of terminal and internal carbon-carbon double bonds in water under mild conditions. Catalysts are prepared on multi-gram scale by pyrolysis of cobalt acetate and uracil, guanine, adenine or l-tryptophan. The most active material Co-Ura/C-600 showed good productivity in industrially relevant hydrogenation of diisobutene to isooctane and in natural oil hardening.

MANUFACTURING METHOD OF NITRYL COMPOUND

PROBLEM TO BE SOLVED: To provide a method for manufacturing a nitryl compound at good efficiency and safety under a moderate reaction condition. SOLUTION: In a manufacturing method of a nitryl compound, an organic compound having a carbon-carbon unsaturated bond and acetone cyanhydrin are reacted in the presence of bivalent nickel compound, an organic phosphorus compound and a metal powder to add a nitryl group to one carbon constituting the carbon-carbon unsaturated bond. The metal powder is selected from zinc, magnesium, aluminum and manganese. The nickel compound is preferably halide salt of nickel, carboxylate of nickel and β-diketo compound salt of nickel. The organic phosphorus compound is preferably triphenylphosphine. The reaction between the organic compound and the acetone cyanhydrin can be conducted at a reaction temperature of 85°C to 90°C in a solvent of an alcohol compound. SELECTED DRAWING: None COPYRIGHT: (C)2017,JPOandINPIT

Efficient nickel-catalyzed hydrocyanation of alkenes using acetone cyanohydrin as a safer cyano source

An active nickel catalyst prepared in situ from a Ni(II) compound, phosphine ligand, and zinc powder was found to be an efficient catalyst system for the hydrocyanation of various alkenes using acetone cyanohydrin as a safer cyano source. The combination of NiCl2·6H2O and 1,3-bis(diphenylphosphino)propane was the most efficient catalyst precursor in DMF. Under the optimized conditions, various styrenes, heterocyclic alkenes, and aliphatic alkenes were converted to their corresponding nitriles in excellent yields.