22627-01-6

Basic information

• Product Name: Benzenemethanimine, 2-methyl-a-(2-methylphenyl)-
• CAS NO: 22627-01-6
• Molecular Formula: C15H15N
• Molecular Weight: 209.291
• Mol File: 22627-01-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzenemethanimine, 2-methyl-a-(2-methylphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanimine, 2-methyl-a-(2-methylphenyl)-(22627-01-6)
• EPA Substance Registry System: Benzenemethanimine, 2-methyl-a-(2-methylphenyl)-(22627-01-6)

Safety Data

• Hazardous Substances Data: 22627-01-6(Hazardous Substances Data)

Upstream product

• 529-19-1 2-Methylbenzonitrile 
• 95-46-5 2-methylphenyl bromide 

Downstream Products

• 1018-97-9 2,2'-dimethylbenzophenone 
• 246853-44-1 2,2'-dimethylbenzhydrylamine 
• 39267-91-9 N-(4-Dimethylaminobutyl)-2,2'-dimethyl-diphenylketoimin 
• 29041-25-6 2,2'-bis(bromomethyl)benzophenone 
• 22978-49-0 2-methyl-N-(2-methylphenyl)benzamide 
• 39265-31-1 N-(2-Diethylaminoethyl)-2,2'-dimethyl-diphenylketoimin 
• 39265-35-5 N-(3-Dimethylaminopropyl)-2,2'-dimethyl-diphenylketoimin 
• 39265-29-7 N-(2-Dimethylaminoethyl)-2,2'-dimethyl-diphenylketoimin 

Relevant articles and documents

A Diastereodivergent and Enantioselective Approach to syn- And anti-Diamines: Development of 2-Azatrienes for Cu-Catalyzed Reductive Couplings with Imines That Furnish Allylic Amines

We introduce a new reagent class, 2-azatrienes, as a platform for catalytic enantioselective synthesis of allylic amines. Herein, we demonstrate their promise by a diastereodivergent synthesis of syn- and anti-1,2-diamines through their Cu-bis(phosphine)-catalyzed reductive couplings with imines. With Ph-BPE as the supporting ligand, anti-diamines are obtained (up to 91% yield, >20:1 dr, and >99:1 er), and with the rarely utilized t-Bu-BDPP, syn-diamines are generated (up to 76% yield, 1:>20 dr, and 97:3 er).