229613-81-4Relevant articles and documents
Steric promotion of aromatic C-H bond activation in primary benzylamines
Dunina, Valery V.,Kuz'mina, Lyudmila G.,Kazakova, Marina Yu.,Gorunova, Ol'ga N.,Grishin, Yury K.,Kazakova, Elena I.
, p. 1029 - 1039 (2007/10/03)
ortho-Palladation of a sterically crowded primary benzylamine, α- phenylneopentylamine, was accomplished in a moderate yield of 50% in the reaction with the weakest of palladation agents (Li2PdCl4) under very mild conditions, due to