23022-40-4

Basic information

• Product Name: Stannane,1H-inden-1-yltrimethyl-
• Synonyms: Stannane,1H-inden-1-yltrimethyl-
• CAS NO: 23022-40-4
• Molecular Formula: C₁₂H₁₆Sn
• Molecular Weight: 278.9654
• Mol File: 23022-40-4.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 293.1°Cat760mmHg
• Flash Point: 134.5°C
• Appearance: /
• Density: g/cm³
• Vapor Pressure: 0.00309mmHg at 25°C
• CAS DataBase Reference: Stannane,1H-inden-1-yltrimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Stannane,1H-inden-1-yltrimethyl-(23022-40-4)
• EPA Substance Registry System: Stannane,1H-inden-1-yltrimethyl-(23022-40-4)

Safety Data

• Hazardous Substances Data: 23022-40-4(Hazardous Substances Data)

Usage

InChI:InChI=1/C9H7.3CH3.Sn/c1-2-5-9-7-3-6-8(9)4-1;;;;/h1-7H;3*1H3;/rC12H16Sn/c1-13(2,3)12-9-8-10-6-4-5-7-11(10)12/h4-9,12H,1-3H3

Upstream product

• 1066-45-1 trimethyltin(IV)chloride 
• 95-13-6 1-indene 
• 20669-47-0 indenyllithium 

Downstream Products

• 77443-71-1 Indenyl o-nitrophenyl sulfide 
• 2177-49-3 1-(1-indenyl)-indene 
• 95-13-6 1-indene 
• 76001-74-6 1-trifluoroacetylindene 
• 67605-31-6 1--inden 

Relevant articles and documents

From Carbanions to Organometallic Compounds: Quantification of Metal Ion Effects on Nucleophilic Reactivities

The influence of the metal on the nucleophilic reactivities of indenyl metal compounds was quantitatively determined by kinetic investigations of their reactions with benzhydrylium ions (Ar2CH+) and structurally related quinone methides. With the correlation equation logk2=sN(N+E), it can be derived that the ionic indenyl alkali compounds are 1018 to 1024 times more reactive (depending on the reference electrophile) than the corresponding indenyltrimethylsilane. Different worlds: Kinetic investigations with reference electrophiles show that a reaction with an electrophile, which would proceed within milliseconds with indenyl lithium, would require much more than the age of the universe with the corresponding organosilicon compound. Met=metal.