77443-71-1Relevant articles and documents
REACTIVITY OF ORGANOTIN COMPOUNDS. XXII. REACTIONS OF ORGANOTIN COMPOUNDS WITH o-NITROBENZENESULFENYL CHLORIDE
Kashin, A. N.,Bumagin, N. A.,Beletskaya, I. P.,Reutov, O. A.
, p. 2190 - 2195 (2007/10/02)
The reaction of organotin compounds RSnMe3 and of cyclohexenyloxytriethyltin (VII) with o-nitrobenzenesulfenyl chloride (VIII) in methylene chloride under vacuum conditions was investigated.In the reactions of the organotin compounds (IV - VII) with o-nitrobenzenesulfenyl chloride (VIII) the corresponding sulfides are formed with quantitative yields.In the reactions ofcompounds (I) and (II) with (VIII) sulfides, fluorenyl dimers, and (o-NO2C6H4S)2 are obtained, and the yield of the sulfides decreases in the presence of atmospheric oxygen.In the reaction of compound (III) with (VIII) only the oxidation products (9-C6H5C13H8)2 and (o-NO2C6H4S)2 are formed.Possible reaction mechanisms are discussed.
