2341-86-8

Basic information

• Product Name: N-Phenyl-2,3,4,5,6-pentafluorobenzenemethanimine
• Synonyms: N-(2,3,4,5,6-Pentafluorobenzylidene)aniline;N-Phenyl-2,3,4,5,6-pentafluorobenzenemethanimine
• CAS NO: 2341-86-8
• Molecular Formula: C₁₃H₆F₅N
• Molecular Weight: 271.19
• Mol File: 2341-86-8.mol
• Article Data: 6

Chemical Properties

• Appearance: /
• CAS DataBase Reference: N-Phenyl-2,3,4,5,6-pentafluorobenzenemethanimine(CAS DataBase Reference)
• NIST Chemistry Reference: N-Phenyl-2,3,4,5,6-pentafluorobenzenemethanimine(2341-86-8)
• EPA Substance Registry System: N-Phenyl-2,3,4,5,6-pentafluorobenzenemethanimine(2341-86-8)

Safety Data

• Hazardous Substances Data: 2341-86-8(Hazardous Substances Data)

Upstream product

• 1478-07-5 2,3,4,5,6-pentafluorobenzoyl fluoride 
• 62-53-3 aniline 
• 827-15-6 1,2,3,4,5-pentafluoro-6-iodobenzene 
• 344-04-7 bromopentafluorobenzene 
• 653-37-2 perfluorobenzaldehyde 
• 107-19-7 propargyl alcohol 

Downstream Products

• 1462334-94-6 (ortho-F₄C₆-CHN-C₆H₅)Co(II)(F)(PMe₃)₂ 
• 63400-33-9 N-<3,4,5-Trifluor-2,6-diphenyl-benzyliden>-anilin 
• 1415929-40-6 N-[(3,4,5-trifluoro-2,6-dimethylphenyl)methylene]aniline 
• 1415929-47-3 N-[(3,4,5,6-tetrafluoro-2-methylphenyl)methylene]aniline 
• 96386-10-6 α-pentafluorophenyl-N-phenylnitrone 
• 58627-19-3 2,3,4,5,6-pentafluoro-N-phenylbenzamide 
• 602-94-8 Pentafluorobenzoic acid 
• 653-37-2 perfluorobenzaldehyde 

Relevant articles and documents

Microwave promoted solvent-free one-pot three-component reaction to 2-pentafluorophenylquinoline derivatives

A novel and efficient one-pot multi-component reaction of pentafluorobenzaldehyde, alkynes and anilines for the synthesis of 2-pentafluorophenyl substituted quinolines under microwave irradiation and a solvent-free condition is presented.

Photoredox Radical/Polar Crossover Enables Construction of Saturated Nitrogen Heterocycles

Photoredox-mediated radical/polar crossover (RPC) processes offer new avenues for the synthesis of cyclic molecules. This process has been realized for the construction of medium-sized saturated nitrogen heterocycles. Photocatalytically generated alkyl ra

Nickel-catalyzed C-F bond activation and alkylation of polyfluoroaryl imines

In this paper we show the C-F bond activation and alkylation in polyfluoroaryl imines. An active trimethylphosphine supported nickel-catalyzed cross-coupling reaction of polyfluoroaryl imines with ZnMe2 under mild conditions is described. According to the in situ 19F NMR spectroscopic data, the substrates are quantitatively converted into di-methylation products, while mono-methylation can also be realized under the controlled conditions in moderate yields. Apart from ZnMe2, other organozinc regents were tried in this system. However, due to the nucleophilicity and steric hindrance, they show much lower reactivity than ZnMe2. Only in the case of benzylic zinc chloride, the dibenzylation product can be obtained quantitatively by raising temperature to 90 °C. The results reported here will benefit the development of C-F bond activation as well as the diversity of Schiff bases.