23803-85-2

Basic information

• Product Name: 2,5-di-tert-butyl-6-hydroxy-1,4-benzoquinone
• Synonyms: 2,5-di-tert-butyl-6-hydroxy-1,4-benzoquinone
• CAS NO: 23803-85-2
• Molecular Weight: 236.311
• Mol File: 23803-85-2.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: 2,5-di-tert-butyl-6-hydroxy-1,4-benzoquinone(CAS DataBase Reference)
• NIST Chemistry Reference: 2,5-di-tert-butyl-6-hydroxy-1,4-benzoquinone(23803-85-2)
• EPA Substance Registry System: 2,5-di-tert-butyl-6-hydroxy-1,4-benzoquinone(23803-85-2)

Safety Data

• Hazardous Substances Data: 23803-85-2(Hazardous Substances Data)

Upstream product

• 15910-86-8 3,6-Di-tert.-butyl-guajacol 
• 67-56-1 methanol 
• 15512-06-8 3,6-di-tert-butylbenzene-1,2-diol 
• 34105-76-5 3,5-di-tert-butyl-1,2-benzoquinone 
• 77145-10-9 3,6-di-tert-butyl-4-methoxy-1,2-benzoquinone 
• 67-64-1 acetone 
• 1020-31-1 3,5-Di-tert-butylcatechol 
• 2444-28-2 2,6-di-tert-butyl-4-hydroxyphenol 
• 88-58-4 2,5-bis(1,1-dimethylethyl)-1,4-benzenediol 
• 108-88-3 toluene 
• 245416-53-9 4-benzyl-3,6-di-tert-butyl-1,2-benzoquinone 
• 75-91-2 tert.-butylhydroperoxide 
• 1310546-19-0 3,6-di-tert-butyl-4-{2-[2-(2-hydroxyethoxy)ethoxy]ethoxy}cyclohexa-3,5-diene-1,2-dione 
• 1310546-16-7 3,6-di-tert-butyl-4-[2-(2-hydroxyethoxy)ethoxy]cyclohexa-3,5-diene-1,2-dione 

Downstream Products

• 146508-35-2 2-triphenylstannyloxy-3,6-di-tert-butyl-1,4-benzoquinone 
• 1428338-37-7 2,5-di(tert-butyl)-3,6-dioxocyclohexa-1,4-dienyl methacrylate 
• 1428338-39-9 2,5-di(tert-butyl)-3,4-dioxocyclohexa-1,5-dienyl methacrylate 
• 152729-24-3 ((CH₃)3C)CCO(Sn(C₆H₅)3)CHC(CH₃)3CCOCOMn(CO)4 
• 152730-54-6 ((CH₃)3C)CCO(Sn(C₆H₅)3)CHC(CH₃)3CCOCOSn(C₆H₅)3 

Relevant articles and documents

OXIDATION AND ALKOXYLATION OF 3,6-DI-TERT-BUTYLPYROCATECHOL CATALYZED BY MANGANESE DIACETATE

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KINETICS AND MECHANISM OF THE REACTION OF OZONE WITH 3,6-DI-tert-BUTYLPYROCATECHOL

The reaction of ozone with 3,6-di-tert-butylpyrocatechol at ca. 20 deg C was investigated, and it was found that the main reaction product was 3,6-di-tert-butylquinone, while the reaction rate was proportional to the concentrations of the reagents.A react

Alkoxylation of 3,6-Di-tert-butyl-1,2-benzoquinone. New Bis-1,2-benzoquinones

Alkoxylation of 3,6-di-tert-butyl-1,2-benzoquinone with a number of diols, including propane-1,3- diol, butane-1,4-diol, di-, and triethylene glycols, and cyclohexane-1,4-diyldimethanol, was studied. Nine new 4-alkoxy-3,6-di-tert- butyl-1,2-benzoquinones were synthesized, four of which were bis-1,2-benzoquinones with different tethers (6-13 atoms) between the quinone fragments. Depending on the length of the chain between the hydroxy groups in glycols, bicyclic 4,5-disubstituted 3,6-di-tert-butyl-1,2-benzoquinones were formed or their stepwise alkoxylation occurred. The newly synthesized o-benzoquinone derivatives can be reduced with alkali metals to give radical anions and converted into semiquinone chelates with manganese carbonyl. Pleiades Publishing, Ltd., 2011.

The reactions of 3,6-di-tert-butyl-1,2-benzoquinone and 3,6-di-tert-butylcatechol with tert-butyl hydroperoxide

Reaction of 3,6-di-tert-butyl-1,2-benzoquinone and 3,6-di-tert-butylcatechol with tert-butyl hydroperoxide in aprotlc solvents leads to the generation of semiquinone (SQ 'H), alkylperoxy (ROO'), and alkyloxy radicals. The reaction of SQ'H and ROO' produces 2,5-di-tert-butyl-6-hydroxy-1,4-benzoquinone, 3,6-di-tert-butyl-1-oxacyclohepta-3,5-diene2,7-dione, and 2,5-di-tert-butyl-3,6-dihydroxy-1,4-benzoquinone. The radical generated from solvent attacks SQ' H at position 4 with C-C bond formation. 4-Benzyl-2,5-di-tert-butyl-6-hydroxycyclohexa-2,5-diene-1-dione produced in this way is transformed into 4-benzyl-3,6-di-tert-butyl-1,2-benzoquinone under the reaction conditions.