238752-82-4

Basic information

• Product Name: methyl 2-[4-methyl-2-(methyloxy)phenyl]-5-hexenethioate
• Synonyms: methyl 2-[4-methyl-2-(methyloxy)phenyl]-5-hexenethioate
• CAS NO: 238752-82-4
• Molecular Weight: 264.389
• Mol File: 238752-82-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: methyl 2-[4-methyl-2-(methyloxy)phenyl]-5-hexenethioate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2-[4-methyl-2-(methyloxy)phenyl]-5-hexenethioate(238752-82-4)
• EPA Substance Registry System: methyl 2-[4-methyl-2-(methyloxy)phenyl]-5-hexenethioate(238752-82-4)

Safety Data

• Hazardous Substances Data: 238752-82-4(Hazardous Substances Data)

Upstream product

• 221354-43-4 2-<4-methyl-2-(methoxy)phenyl>-1-tetrahydro-2H-1,4-oxazin-4-yl-1-ethanthione 
• 35633-35-3 2-methoxy-4-methylacetophenone 
• 122-46-3 3-acetoxytoluene 
• 6921-64-8 4'-hydroxy-2'-methylacetophenone 
• 7766-51-0 4-iodobut-1-ene 
• 221354-52-5 methyl 2-<4-methyl-2-methoxyphenyl>ethanethioate 

Downstream Products

• 64052-99-9 rel-(3S,3aS,8bS)-7-bromo-3,6,8b-trimethyl-2,3,3a,8b-tetrahydro-1H-benzo[b]cyclopenta[d]furan-3a-carbaldehyde 

Relevant articles and documents

The synthesis of a natural product family: From debromoisolaurinterol to the aplysins

Total syntheses of (±)-aplysin 1, (±)-debromoaplysin 2, (±)-isoaplysin 3, (±)-aplysinol 4, (±)-debromoaplysinol 5, (±)-aplysinal 6, (±)-isolaurinterol 7 and (±)-debromoisolaurinterol 8 are described. Key features are a diastereoselective, sulfur mediated radical cyclisation of diene 12 to give 35; a new radical to polar crossover sequence mediated by Bu3Sn that transforms diene 12 into (±)-debromoisolaurinterol 8; and a series of biomimetic cyclisation and oxidation reactions.