242809-41-2

Basic information

• Product Name: Benzoic acid (R)-1-[(1R,5R,7S,8R)-7-bromomethyl-8-(2,2-dimethyl-propionyloxymethyl)-4,7-dimethyl-6-oxa-bicyclo[3.2.1]oct-3-en-5-ylmethyl]-prop-2-ynyl ester
• Synonyms: Benzoic acid (R)-1-[(1R,5R,7S,8R)-7-bromomethyl-8-(2,2-dimethyl-propionyloxymethyl)-4,7-dimethyl-6-oxa-bicyclo[3.2.1]oct-3-en-5-ylmethyl]-prop-2-ynyl ester
• CAS NO: 242809-41-2
• Molecular Weight: 517.46
• Mol File: 242809-41-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzoic acid (R)-1-[(1R,5R,7S,8R)-7-bromomethyl-8-(2,2-dimethyl-propionyloxymethyl)-4,7-dimethyl-6-oxa-bicyclo[3.2.1]oct-3-en-5-ylmethyl]-prop-2-ynyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid (R)-1-[(1R,5R,7S,8R)-7-bromomethyl-8-(2,2-dimethyl-propionyloxymethyl)-4,7-dimethyl-6-oxa-bicyclo[3.2.1]oct-3-en-5-ylmethyl]-prop-2-ynyl ester(242809-41-2)
• EPA Substance Registry System: Benzoic acid (R)-1-[(1R,5R,7S,8R)-7-bromomethyl-8-(2,2-dimethyl-propionyloxymethyl)-4,7-dimethyl-6-oxa-bicyclo[3.2.1]oct-3-en-5-ylmethyl]-prop-2-ynyl ester(242809-41-2)

Safety Data

• Hazardous Substances Data: 242809-41-2(Hazardous Substances Data)

Upstream product

• 65-85-0 benzoic acid 
• 242809-37-6 2,2-Dimethyl-propionic acid (1R,5R,7S,8R)-7-bromomethyl-5-((S)-2-hydroxy-but-3-ynyl)-4,7-dimethyl-6-oxa-bicyclo[3.2.1]oct-3-en-8-ylmethyl ester 
• 242809-82-1 (1R,5R,7S,8R)-7-Bromomethyl-5-[(S)-2-(tert-butyl-dimethyl-silanyloxy)-but-3-ynyl]-8-(tert-butyl-dimethyl-silanyloxymethyl)-4,7-dimethyl-6-oxa-bicyclo[3.2.1]oct-3-ene 
• 242809-83-2 (S)-1-((1R,5R,7S,8R)-7-Bromomethyl-8-hydroxymethyl-4,7-dimethyl-6-oxa-bicyclo[3.2.1]oct-3-en-5-yl)-but-3-yn-2-ol 
• 172172-74-6 [(1R,5R,7S,8R)-7-Bromomethyl-8-(tert-butyl-dimethyl-silanyloxymethyl)-4,7-dimethyl-6-oxa-bicyclo[3.2.1]oct-3-en-5-yl]-acetonitrile 
• 172172-73-5 [(1R,5R,6R)-6-(tert-Butyl-dimethyl-silanyloxymethyl)-1-hydroxy-5-isopropenyl-2-methyl-cyclohex-2-enyl]-acetonitrile 
• 138459-91-3 3-pivaloyl-1,3-thiazolidine-2-thione 

Downstream Products

• 35481-77-7 corianine 
• 17617-45-7 picrotoxinin 

Relevant articles and documents

Palladium-catalyzed enyne cycloisomerization reaction in an asymmetric approach to the picrotoxane sesquiterpenes. 2. Second-generation total syntheses of corianin, picrotoxinin, picrotin, and methyl picrotoxate

An alternative, more efficient synthesis of the picrotoxane core by palladium-catalyzed cycloisomerization of an enyne requires the design of a new catalyst system based upon 1,3-bis(dibenzophospholyl)propane and 2- (diphenylphosphino)benzoic acid as liga