24425-97-6Relevant articles and documents
KINETIC CHARACTERISTICS OF SUBSTITUTIONAL CHLORINATION OF TETRACHLOROPROPANE IN PRESENCE OF DICHLOROPROPENE.
Evstigneev,Levanova,Berlin,Rodova,Lebedev
, p. 1372 - 1376 (2007/10/02)
The purpose of this investigation is to determine the kinetic characteristics of this process, which are to form the basis of a model of the chlorination reactor. It is found that the activation energy E equals 43. 22 plus or minus 1. 78 kJ/mole for the reaction of substitutional chlorination of TCP in presence of DCP is considerably lower than the activation energy of thermal chlorination (83. 7-104. 7 kJ/mole), confirming the existence of an inductive effect in additive chlorination in a system of concurrent reactions I and II.