24808-73-9

Basic information

• Product Name: (Z)-(3-methoxyprop-1-en-1-yl)benzene
• CAS NO: 24808-73-9
• Molecular Weight: 148.205
• Mol File: 24808-73-9.mol
• Article Data: 57

Chemical Properties

• CAS DataBase Reference: (Z)-(3-methoxyprop-1-en-1-yl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-(3-methoxyprop-1-en-1-yl)benzene(24808-73-9)
• EPA Substance Registry System: (Z)-(3-methoxyprop-1-en-1-yl)benzene(24808-73-9)

Safety Data

• Hazardous Substances Data: 24808-73-9(Hazardous Substances Data)

Upstream product

• 4407-36-7 (2E)-3-phenyl-2-propen-1-ol 
• 74-88-4 methyl iodide 
• 22554-02-5 ethyl cinnamylcarbamate 
• 124-41-4 sodium methylate 
• 123-91-1 1,4-dioxane 
• 22665-13-0 1-phenylallyl methyl ether 
• 7637-07-2 boron trifluoride 
• 67-56-1 methanol 
• 300-57-2 allylbenzene 
• 1445-45-0 Trimethyl orthoacetate 
• 149-73-5 trimethyl orthoformate 
• 100-42-5 styrene 
• 2243-53-0 trans-styrylacetic acid 
• 24808-73-9 (E)-(3-methoxyprop-1-en-1-yl)benzene 

Downstream Products

• 99857-56-4 (1RS,2SR)-2-bromo-1,3-dimethoxy-1-phenyl-propane 
• 99359-87-2 1-chloro-3-methoxy-1-phenyl-acetone oxime 
• 51985-30-9 4-Methyl-N-[(E)-3-phenyl-prop-2-en-(E)-ylidene]-benzenesulfonamide 
• 82053-18-7 1-[(E)-3-methoxyhexa-1,5-dienyl]benzene 
• 120342-90-7 trans-2-Methoxymethyl-3-phenyl-ethoxycarbonylcyclopropane 
• 120342-93-0 (2S,3S)-2-Methoxy-1,3-diphenyl-pent-4-en-1-one 
• 120342-93-0 (2S,3R)-2-Methoxy-1,3-diphenyl-pent-4-en-1-one 
• 120342-91-8 ((2R,3R)-2-Methoxymethyl-3-phenyl-cyclopropyl)-phenyl-methanone 
• 120342-92-9 ((2R,3R)-2-Methoxymethyl-3-phenyl-cyclopropyl)-(4-methoxy-phenyl)-methanone 
• 120342-95-2 (2S,3R)-2-Methoxy-1-(4-methoxy-phenyl)-3-phenyl-pent-4-en-1-one 
• 120342-95-2 (2S,3S)-2-Methoxy-1-(4-methoxy-phenyl)-3-phenyl-pent-4-en-1-one 
• 3412-44-0 (1E)-1,3-diphenylpropene 
• 14371-10-9 (E)-3-phenylpropenal 
• 873-66-5 1-propenylbenzene 

Relevant articles and documents

Decarboxylative cross-nucleophile coupling via ligand-to-metal charge transfer photoexcitation of Cu(ii) carboxylates

Reactions that enable carbon–nitrogen, carbon–oxygen and carbon–carbon bond formation lie at the heart of synthetic chemistry. However, substrate prefunctionalization is often needed to effect such transformations without forcing reaction conditions. The development of direct coupling methods for abundant feedstock chemicals is therefore highly desirable for the rapid construction of complex molecular scaffolds. Here we report a copper-mediated, net-oxidative decarboxylative coupling of carboxylic acids with diverse nucleophiles under visible-light irradiation. Preliminary mechanistic studies suggest that the relevant chromophore in this reaction is a Cu(ii) carboxylate species assembled in situ. We propose that visible-light excitation to a ligand-to-metal charge transfer (LMCT) state results in a radical decarboxylation process that initiates the oxidative cross-coupling. The reaction is applicable to a wide variety of coupling partners, including complex drug molecules, suggesting that this strategy for cross-nucleophile coupling would facilitate rapid compound library synthesis for the discovery of new pharmaceutical agents. [Figure not available: see fulltext.].

Stereoselective Rhodium-Catalyzed Isomerization of Stereoisomeric Mixtures of Arylalkenes

A new efficient method for the synthesis of a high ratio of E -alkenes from E / Z mixtures of alkenes with B 2pin 2in the presence of a rhodium catalyst is described. This reaction features mild reaction conditions, broad functional group tolerance, and highly great application potential.

Design, Synthesis, and Application of Chiral C2-Symmetric Spiroketal-Containing Ligands in Transition-Metal Catalysis

We present an expedient and economical route to a new spiroketal-based C2-symmetric chiral scaffold, termed SPIROL. Based on this spirocyclic scaffold, several chiral ligands were generated. These ligands were successfully employed in an array of stereoselective transformations, including in iridium-catalyzed hydroarylations (up to 95 % ee), palladium-catalyzed allylic alkylations (up to 97 % ee), intermolecular palladium-catalyzed Heck couplings (up to 94 % ee), and rhodium-catalyzed dehydroalanine hydrogenation (up to 93 % ee).