24858-28-4Relevant articles and documents
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Geisman,Schlatter
, p. 771 (1946)
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Pezold,Shriner
, p. 4707,4710 (1932)
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Oxidation of α-oxo-oximes to nitrile oxides with hypervalent iodine reagents
Jen, Tim,Mendelsohn, Brian A.,Ciufolini, Marco A.
supporting information; experimental part, p. 728 - 731 (2011/03/22)
Upon reaction with PhI(OAc)2, α-oxo-aldoximes are oxidized to α-oxo-nitrile oxides, while α-oxo-ketoximes are converted into nitrile oxides via the oxidative cleavage of the carbonyl-imino σ bond. The nitrile oxides thus formed were trapped wit
ORGANIC SYNTHESIS USING ORGANOSULFUR-NITRITES AND -NITRATES
Kim, Yong Hae
, p. 249 - 260 (2007/10/02)
Thionitrites or thionitrates have been considered to be unstable.However, bulky groups' thio-NOn such as t-butylthio-nitrites and -nitrates have been readily synthesized and found to be stable enough for the use of the useful organic syntheses as an excellent nitrosation and diazotization reagents under mild conditions.Direct conversion of amines to the corresponding halides in the presence of copper halides (II), fluorination of heterocyclic amines in the presence of sodium tetrafluoroborate, α- oximation of methylene groups in ketones, facile cleavage of C=N bond to ketones, and desulfurization of thioacetals and thioketals, and other useful organic syntheses are described.