25186-92-9

Basic information

• Product Name: Phenyl 4-bromophenyl sulfoxide
• Synonyms: (p-Bromophenyl)phenyl sulfoxide;p-Bromophenylphenyl sulfoxide;Phenyl 4-bromophenyl sulfoxide;Phenyl(4-bromophenyl) sulfoxide
• CAS NO: 25186-92-9
• Molecular Formula: C₁₂H₉BrOS
• Molecular Weight: 281.17
• Mol File: 25186-92-9.mol
• Article Data: 21

Chemical Properties

• Boiling Point: 398.8°C at 760 mmHg
• Flash Point: 195°C
• Appearance: /
• Density: 1.61g/cm³
• Vapor Pressure: 3.31E-06mmHg at 25°C
• Refractive Index: 1.71
• CAS DataBase Reference: Phenyl 4-bromophenyl sulfoxide(CAS DataBase Reference)
• NIST Chemistry Reference: Phenyl 4-bromophenyl sulfoxide(25186-92-9)
• EPA Substance Registry System: Phenyl 4-bromophenyl sulfoxide(25186-92-9)

Safety Data

• Hazardous Substances Data: 25186-92-9(Hazardous Substances Data)

Usage

InChI:InChI=1/C12H9BrOS/c13-10-6-8-12(9-7-10)15(14)11-4-2-1-3-5-11/h1-9H

Upstream product

• 106-53-6 para-bromobenzenethiol 
• 5467-74-3 4-Bromophenylboronic acid 
• 98-80-6 phenylboronic acid 
• 591-50-4 iodobenzene 
• 589-87-7 1,4-bromoiodobenzene 
• 65662-88-6 phenyl(4-bromophenyl)sulfide 
• 66003-76-7 Diphenyliodonium triflate 
• 108-98-5 thiophenol 
• 56075-37-7 1-(methylsulfonyl)-2-(4-bromophenyl)diazene 

Downstream Products

• 349498-79-9 trans-[Pt(SC₆H₄Br)(P(C₆H₅)3)2(COC₆H₅)] 
• 65662-88-6 phenyl(4-bromophenyl)sulfide 

Relevant articles and documents

Synergistic cooperative effect of CF3SO2Na and bis(2-butoxyethyl)ether towards selective oxygenation of sulfides with molecular oxygen under visible-light irradiation

A safe, practical and eco-friendly method for the switchable synthesis of sulfoxides and sulfones through visible-light-initiated oxygenation of sulfides at ambient temperature under transition-metal-, additives-free and minimal solvent conditions. The synergistic catalytic efforts between CF3SO2Na and 2-butoxyethyl ether represents the key promoting factor for the reaction. This journal is

g-C3N4/H3PW4Mo8O40 S-scheme photocatalyst with enhanced photocatalytic oxidation of alcohols and sulfides

In this work, graphitic carbon nitride (g-C3N4) decorated with molybdenum-substituted tungstophosphoric acid as a novel photocatalyst (H3PW4Mo8O40/g-C3N4) was used to catalyze the oxidation of alcohols and sulfides. H3PW4Mo8O40/g-C3N4 (PW4Mo8/g-C3N4) displays higher photocatalytic activity under visible light irradiation for the oxidation of alcohols and sulfides compared with Keggin/g-C3N4 (PW12/g-C3N4). To obtain the optimum value, molybdenum substitution contents (H3PW12-xMoxO40) were changed from x = 4 to 12. The results showed that PW4Mo8 produces the best yield under visible-light irradiation. The results showed that PW4Mo8 was the best sample. The reaction rate increase can be due to the redox and acid properties of PW4Mo8/g-C3N4. This study provides a new insight for the preparation of highly efficient photocatalysts for the oxidation of organic compounds.

Room temperature nickel-catalyzed cross-coupling of aryl-boronic acids with thiophenols: Synthesis of diarylsulfides

A NiCl2/2,2′-bipyridine-catalyzed cross-coupling of thiophenols with arylboronic acids has been developed for the synthesis of symmetric and unsymmetric diarylsulfides at room temperature and in air. This methodology is reliable and offers a mild and easy to operate process for the synthesis of arylthioethers, which are essential compounds with applications in the pharmaceutical and agricultural industries. This method avoids the use of expensive transition metals, such as Pd, Ir or Rh, sophisticated ligands and elevated temperatures. It also has a wide substrate scope (55 examples) and provides products in good to excellent yields (72-93%).