25310-92-3

Basic information

• Product Name: (1,1-dimethoxypropyl)benzene
• Synonyms: (1,1-Dimethoxypropyl)benzene; benzene, (1,1-dimethoxypropyl)-
• CAS NO: 25310-92-3
• Molecular Formula: C₁₁H₁₆O₂
• Molecular Weight: 180.2435
• Mol File: 25310-92-3.mol
• Article Data: 10

Chemical Properties

• Boiling Point: 211.43°C at 760 mmHg
• Flash Point: 63.206°C
• Density: 0.972g/cm³
• Vapor Pressure: 0.265mmHg at 25°C
• Refractive Index: 1.481
• CAS DataBase Reference: (1,1-dimethoxypropyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (1,1-dimethoxypropyl)benzene(25310-92-3)
• EPA Substance Registry System: (1,1-dimethoxypropyl)benzene(25310-92-3)

Safety Data

• Hazardous Substances Data: 25310-92-3(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 10147-11-2 propargyl benzene 
• 24823-81-2 trimethoxypropane 
• 100-52-7 benzaldehyde 
• 93-55-0 1-phenyl-propan-1-one 
• 149-73-5 trimethyl orthoformate 
• 673-32-5 1-Phenylprop-1-yne 

Downstream Products

• 93-58-3 benzoic acid methyl ester 
• 4165-86-0 (E)-(1-ethylpropenyl)benzene 
• 91922-61-1 1-hydroperoxy-1-methoxy-1-phenylpropane 
• 1227489-49-7 PhC(OCH₂Ph)2Et 
• 93-55-0 1-phenyl-propan-1-one 
• 1227489-26-0 (Z)-N-(3-methoxy-3-phenylpentylidene)-2-methylpropan-2-amine oxide 
• 1227489-45-3 (Z)-N-(3-methoxy-2,3-diphenylpentylidene)-2-methylpropan-2-amine oxide 
• 1227489-43-1 (Z)-N-[2-(1-methoxy-1-phenylpropyl)heptylidene]-2-methylpropan-2-amine oxide 
• 1227489-41-9 (Z)-N-(3-methoxy-2-methyl-3-phenylpentylidene)-2-methylpropan-2-amine oxide 
• 470467-32-4 4,4,4-trichloro-2-methyl-1-phenylbutane-1,3-dione 

Relevant articles and documents

Conjugate addition of acetal-derived benzyl radicals generated from low-valent titanium-mediated CO bond cleavage

A new method for the generation of benzyl radicals from acetals via low-valent titanium-mediated homolytic CO bond cleavage is presented. The low cost and availability of the developed titanium reagent enable efficient access to α-alkoxy carbon radical species via the developed reaction.

Photocatalytic Reductive Formation of α-Tertiary Ethers from Ketals

A general photocatalytic reductive strategy for the construction of unsymmetrical α-tertiary dialkyl ethers is reported. By merging Lewis acid-mediated ketal activation and visible-light photocatalytic reduction, in situ-generated α-alkoxy radicals were found to engage in addition reactions with a variety of olefinic partners. Good reaction efficiency is demonstrated with a range of ketals of aromatic and aliphatic ketones. Extension to acetal substrates is also described, demonstrating the overall synthetic utility of this methodology for complex ether synthesis.

Utilization of hexabromoacetone for protection of alcohols and aldehydes and deprotection of acetals, ketals, and oximes under UV irradiation

Hexabromoacetone (HBA) was efficiently used for the protection of alcohols and aldehydes and deprotection of benzaldehyde dimethyl acetal, solketal, and other acetals and ketals. In only 10?min, the protection of glycerol yielded 90% of solketal and protection of benzaldehyde gave 95% of benzaldehyde dimethyl acetal. The deprotection of benzaldehyde dimethyl acetal under UV irradiation gave over 90% yield of benzaldehyde within 15?s using only 2.5?mol% of HBA. HBA was also successfully used for deoximation. Solvent was found to play an important role in the efficiency of HBA for these reactions.