25650-53-7Relevant articles and documents
NH4I-mediated three-component coupling reaction: Metal-free synthesis of β-alkoxy methyl sulfides from DMSO, alcohols, and styrenes
Gao, Xiaofang,Pan, Xiaojun,Gao, Jian,Jiang, Huanfeng,Yuan, Gaoqing,Li, Yingwei
, p. 1038 - 1041 (2015)
A novel synthesis recipe for β-alkoxy methyl sulfides was developed via NH4I-mediated three-component oxysulfenylation reaction of styrenes with DMSO and alcohols. This method features simple operation and readily available starting materials, and it provides an alternative sulfenylating agent generated from DMSO for oxysulfenylation reactions.
Zirconocene Catalysis in Organoaluminum Synthesis of 1-Alkenyl Sulfones and Sulfides
Kadikova, Rita N.,Ramazanov, Ilfir R.,Vyatkin, Alexey V.,Dzhemilev, Usein M.
, p. 1889 - 1897 (2017/04/06)
The Cp2ZrCl2-catalyzed methylalumination of 1-alkynyl sulfones and 1-alkynyl sulfides with Me3Al, followed by deuterolysis or hydrolysis, affords the corresponding β,β-disubstituted 1-alkenyl sulfones and 1-alkenyl sulfides in high yields. S-Methyl methanethiosulfonate is shown to be a convenient and efficient sulfanylating agent for 1-alkenylaluminum derivatives.
Reaction of dimethyl sulfide ditriflate with alkenes. Synthesis of sulfur derivatives of nortricyclane
Nenajdenko, Valentine G.,Vertelezkij, Pavel V.,Gridnev, Ilya D.,Shevchenko, Nikolai E.,Balenkova, Elizabeth S.
, p. 8173 - 8180 (2007/10/03)
The reaction of dimethyl sulfide ditriflate with alkenes leads to the corresponding sulfonium salts. Dependence of the reaction course on the substrate structure is discussed. In the reactions with norbornene and norbornadiene the sulfonium salts with nortricyclene skeleton were obtained. The configurations of the two isomeric disubstituted nortricyclanes 21a,b were determined by NMR.
