25692-18-6Relevant articles and documents
Bronsted acid catalyzed formal insertion of isocyanides into a C-O bond of acetals
Tobisu, Mamoru,Kitajima, Aki,Yoshioka, Sachiko,Hyodo, Isao,Oshita, Masayuki,Chatani, Naoto
, p. 11431 - 11437 (2007)
The Bronsted acid catalyzed formal insertion of an isocyanide into a C-O bond of an acetal is described. A diverse array of acyclic and cyclic acetals can be applied to the catalytic insertion to form α-alkoxy imidates. Functional groups, such as nitro, c
Hydrogenolysis of 1-alkoxybenzocyclobutenes with site-selective cleavage of the sterically hindered C(sp2)-C(sp3) bond
Sawano, Shota,Ishida, Naoki,Murakami, Masahiro
, p. 1521 - 1523 (2015/11/24)
1-Alkoxybenzocyclobutenes undergo ring-opening hydrogenolysis with site-selective cleavage of the sterically hindered C(sp2)-C(sp3) bond on Pd/C.
Rearrangement of Carboxylates derived from N-Acetyl-N-nitroso-&α-amino-acids
Chow, Yuan L.,Polo, Joel
, p. 297 - 299 (2007/10/02)
While N-acetyl-N-nitrosophenylalanine thermally decomposes by the known mechanism, its carboxylate anion undergoes facile rearrangements initiated by carboxylate attack in methanol or water to give 2-methoxy- or 2-hydroxy-3-phenylpropanoic acid, respectively.
