2591-78-8

Basic information

• Product Name: Formamide,N-hexyl-
• Synonyms: N-Formyl-n-hexylamine;N-Hexylformamide; NSC 55752
• CAS NO: 2591-78-8
• Molecular Formula: C₇H₁₅NO
• Molecular Weight: 129.2001
• Mol File: 2591-78-8.mol
• Article Data: 7

Chemical Properties

• Boiling Point: 245.1°Cat760mmHg
• Flash Point: 135.7°C
• Appearance: /
• Density: 0.86g/cm³
• Vapor Pressure: 0.0292mmHg at 25°C
• Refractive Index: 1.423
• CAS DataBase Reference: Formamide,N-hexyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Formamide,N-hexyl-(2591-78-8)
• EPA Substance Registry System: Formamide,N-hexyl-(2591-78-8)

Safety Data

• Hazardous Substances Data: 2591-78-8(Hazardous Substances Data)

Usage

InChI:InChI=1/C7H15NO/c1-2-3-4-5-6-8-7-9/h7H,2-6H2,1H3,(H,8,9)

Upstream product

• 592-41-6 1-hexene 
• 77287-34-4 formamide 
• 67-56-1 methanol 
• 111-26-2 hexan-1-amine 
• 201230-82-2 carbon monoxide 
• 89399-21-3 N-hexyl-4-nitrobenzamide 
• 927902-57-6 1-hexyl-3-methylimidazolium dicyanamide 
• 34825-70-2 hex-5-en-1-amine 
• 124-38-9 carbon dioxide 
• 64-18-6 formic acid 
• 646-14-0 1-nitrohexane 
• 92412-01-6 S-hexyl N-hexylthiocarbamate 

Downstream Products

• 234449-91-3 4-methyl-N-hexylbenzamide 
• 1453815-74-1 5-[(3,5-Dinitrobenzyl)selanyl]-1-hexyl-1H-tetrazole 
• 1453815-73-0 5-benzylselanyl-1-hexyl-1H-tetrazole 
• 15586-23-9 n-hexyl isocyanide 
• 35161-70-7 N-methylhexanamine 

Relevant articles and documents

Catalytic Hydrogenation of Thioesters, Thiocarbamates, and Thioamides

Direct hydrogenation of thioesters with H2 provides a facile and waste-free method to access alcohols and thiols. However, no report of this reaction is documented, possibly because of the incompatibility of the generated thiol with typical hydrogenation catalysts. Here, we report an efficient and selective hydrogenation of thioesters. The reaction is catalyzed by an acridine-based ruthenium complex without additives. Various thioesters were fully hydrogenated to the corresponding alcohols and thiols with excellent tolerance for amide, ester, and carboxylic acid groups. Thiocarbamates and thioamides also undergo hydrogenation under similar conditions, substantially extending the application of hydrogenation of organosulfur compounds.

A Titanium Dioxide Supported Gold Nanoparticle Catalyst for the Selective N-Formylation of Functionalized Amines with Carbon Dioxide and Hydrogen

A TiO2-supported, gold nanoparticle catalyst was found to allow the N-formylation of various amines, including normally unreactive anilines, by using CO2 as the carbonyl source under a H2 atmosphere. A series of reducible functional groups, such as olefins, halogens, carbonyls, carbamates, and cyano moieties, were completely retained during the formylation, which proved the highly selective nature of the formylation reaction. The catalyst was also found to be reusable without any loss of activity or selectivity.

HOLOGRAPHIC STORAGE MEDIUM

Disclosed herein are novel amidic nitrone and a method of manufacturing a data storage media comprising mixing the amidic nitrone, as a photochromic dye, with an organic material or an inorganic material to form a holographic composition and molding the holographic composition into holographic data storage media. Disclosed herein too is an article comprising a photochromic dye and an organic material, wherein the article is used as a data storage media. Disclosed herein too is a method for recording information comprising irradiating an article that comprises a photochromic dye, wherein the irradiation is conducted with electromagnetic energy having a wavelength of about 350 to about 1,100 nanometers; and reacting the photochromic dye.