2592-58-7

Basic information

• Product Name: PENTA-O-BENZOYL-Β-D-GLUCOPYRANOSE, 95% HPLC
• Synonyms: PENTA-O-BENZOYL-Β-D-GLUCOPYRANOSE, 95% HPLC;Penta-O-benzoyl-D-glucopyranose
• CAS NO: 2592-58-7
• Molecular Formula: C₄₁H₃₂O₁₁
• Molecular Weight: 700.68618
• Mol File: 2592-58-7.mol
• Article Data: 79

Chemical Properties

• Boiling Point: 803.7±65.0 °C(Predicted)
• Appearance: /
• Density: 1.37±0.1 g/cm3(Predicted)
• CAS DataBase Reference: PENTA-O-BENZOYL-Β-D-GLUCOPYRANOSE, 95% HPLC(CAS DataBase Reference)
• NIST Chemistry Reference: PENTA-O-BENZOYL-Β-D-GLUCOPYRANOSE, 95% HPLC(2592-58-7)
• EPA Substance Registry System: PENTA-O-BENZOYL-Β-D-GLUCOPYRANOSE, 95% HPLC(2592-58-7)

Safety Data

• Hazardous Substances Data: 2592-58-7(Hazardous Substances Data)

Upstream product

• 530-26-7 D-Mannose 
• 98-88-4 benzoyl chloride 
• 14218-11-2 2,3,4,6-Tetra-O-benzoyl-α-D-mannopyranosyl bromide 
• 97590-76-6 benzyl-O-β-D-glucopyranoside 
• 582-52-5 1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 
• 100-44-7 benzyl chloride 
• 18685-18-2 3-O-benzyl-1,2-5,6-O-diisopropylidene-α-D-glucofuranose 
• 10257-28-0 D-Galactose 
• 2280-44-6 D-Glucose 
• 492-62-6 alpha-D-glucopyranose 
• 105376-04-3 ethyl 2,3,4,6-tetra-O-benzoyl-1-thio-β-D-galactopyranoside 
• 65-85-0 benzoic acid 
• 7296-64-2 β-D-galactopyranoside 
• 59-23-4 D-Galactose 

Downstream Products

• 14218-11-2 2,3,4,6-tetra-O-benzoylglucosyl bromide 
• 212128-08-0 phenyl 2,3,4,6-tetra-O-benzoyl-β-D-galactopyranosyl-(1->6)-2,3,4-tri-O-benzoyl-1-thio-β-D-galactopyranoside 
• 6605-40-9 methyl 2,3,4,6-tetra-O-benzoyl-α-D-mannopyranoside 
• 113544-59-5 O²,O³,O⁴,O⁶-Tetrabenzoyl-D-mannose 
• 2592-58-7 1,2,3,4,6-penta-O-benzoyl-α-D-mannopyranoside 
• 6605-40-9 methyl 2,3,4,6-tetra-O-benzyl-β-D-glucopyranoside 
• 14726-07-9 2,3,4,6-tetra-O-benzoyl-α-D-mannopyranosyl iodide 
• 64768-20-3 2,3,4,6-tetra-O-benzoyl-α-D-mannopyranoside 
• 627466-64-2 2,3,4,6-tetra-O-benzoyl-D-glucopyranose 
• 188435-38-3 bromide 2,3,4,6-tetra-O-Bz-α-D-galactopyranosyl bromide 
• 172847-85-7 (2R,3R,4S,5R,6S)-2-((benzoyloxy)methyl)-6-(p-tolylthio)tetrahydro-2H-pyran-3,4,5-triyl tribenzoate 
• 1228755-39-2 allyl 2,3,4,6-tetra-O-benzoyl-β-D-galactopyranoside 
• 125367-09-1 pent-4-enyl 2,3,4,6-tetra-O-benzoyl-β-D-galactopyranoside 
• 191276-09-2 2,3,4,6-tetra-O-benzoyl-α-D-galactopyranosyl trichloroacetimidate 

Relevant articles and documents

Synthesis and inhibition of α-glucosidase of methyl glycyrrhetinate glycosides

The synthesis of the methyl glycyrrhetinate glycosides and inhibition of α-glucosidase were studied. The carboxyl group of glycyrrhetinic acid was methylated, and glucose and galactose were introduced into the hydroxyl group to obtain compounds 7 and 12.

A Substituent-Directed Strategy for the Selective Synthesis of L-Hexoses: An Expeditious Route to L-Idose

L-Hexoses are rare but biologically significant components of various important biomolecules. However, most are prohibitively expensive (if commercially available) which limits their study and biotechnological exploitation. New, efficient methods to access L-hexoses and their derivatives are thus of great interest. In a previous study, we showcased a stereoselective Bu3SnH-mediated transformation of a 5-C-bromo-D-glucuronide to an L-iduronide. We have now drawn inspiration from this result to derive a new methodology – one that can be harnessed to access other L-hexoses. DFT calculations demonstrate that a combination of a β-F at the anomeric position and a methoxycarbonyl substituent at C-6 is key to optimising the selectivity for the L-hexose product. Our investigations have also culminated in the development of the shortest known synthetic route to a derivative of L-idose from a commercially available starting material (45 % yield over 3 steps). Collectively, these results address the profound lack of understanding of how to synthesise L-hexoses in a stereoselective fashion.

Preparation method of glycyrrhetinic acid glucoside and application of glycyrrhetinic acid glucoside in sweetening agents

The invention relates to a synthetic route of glycyrrhetinic acid glucoside and application of glycyrrhetinic acid glucoside in sweetening agents, and belongs to the field of synthesis of novel sweetening agents. The novel sweetening agent with higher swe