26532-23-0

Basic information

• Product Name: (Z)-3,3-DIMETHYLCYCLOHEXYLIDENEETHANOL
• Synonyms: (z)-2-(3,3-dimethylcyclohexylidene)ethanol;-, Z;3-dimethylcyclohexylidene)-2-((z)-ethano;Ethanol, 2-(3,3-dimethylcyclohexylidene)-, (Z)-;Ethanol, 2-3,3-dimethylcyclohexylidene;(Z)-3,3-DIMETHYLCYCLOHEXYLIDENEETHANOL;GRANDLURE II;GrandlureII,Z-Isomerof
• CAS NO: 26532-23-0
• Molecular Formula: C₁₀H₁₈O
• Molecular Weight: 154.25
• Mol File: 26532-23-0.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 212.7±8.0℃ (760 Torr)
• Flash Point: 90.0±8.3℃
• Appearance: /
• Density: 0.966±0.06 g/cm3 (20 ºC 760 Torr)
• Refractive Index: 1.4771 (25℃)
• CAS DataBase Reference: (Z)-3,3-DIMETHYLCYCLOHEXYLIDENEETHANOL(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-3,3-DIMETHYLCYCLOHEXYLIDENEETHANOL(26532-23-0)
• EPA Substance Registry System: (Z)-3,3-DIMETHYLCYCLOHEXYLIDENEETHANOL(26532-23-0)

Safety Data

• Hazardous Substances Data: 26532-23-0(Hazardous Substances Data)

Usage

General Description

"(Z)-3,3-DIMETHYLCYCLOHEXYLIDENEETHANOL" is a chemical compound with a molecular formula of C10H20O. (Z)-3,3-DIMETHYLCYCLOHEXYLIDENEETHANOL is a cyclohexylideneethanol derivative with a (Z) configuration. It is a colorless liquid with a strong, pungent odor and is insoluble in water but soluble in organic solvents. (Z)-3,3-DIMETHYLCYCLOHEXYLIDENEETHANOL is commonly used in the synthesis of various pharmaceuticals and agrochemicals. It is also used as a fragrance ingredient in personal care and household products. Additionally, it has potential applications as a chemical intermediate in the production of other organic compounds. The compound is known to have low toxicity and is considered safe for use in the specified applications.

InChI:InChI=1/C10H18O/c1-8(11)9-5-4-6-10(2,3)7-9/h11H,4-7H2,1-3H3/b9-8-

Upstream product

• 5629-80-1 (1-hydroxy-3,3-dimethyl-cyclohexyl)-acetic acid ethyl ester 
• 30346-22-6 3,3-Dimethyl-1-hydroxy-cyclohexylessigsaeure 
• 55298-92-5 methyl 3-methylene-7-methyl-6-octenoate 
• 4698-08-2 (E)-geranic acid 
• 121618-03-9 (E)-6-oxo-2-ochtoden-1-yl 3,5-dinitrobenzoate 
• 121617-96-7 (E)-2-ochtoden-1-ol tetrahydropyranyl ether 
• 82528-42-5 (2E)-1-hydroxy-2-ochtoden-6-one 
• 121618-01-7 (EZ)-6-oxo-2-ochtoden-1-yl formate 
• 121617-99-0 Formic acid 2-[4-hydroxy-3,3-dimethyl-cyclohex-(Z)-ylidene]-ethyl ester 
• 132830-39-8 5,5-dimethyl-2-(tetrahydropyranyloxymethyl)-1-oxaspiro<2.5>-octane 
• 82528-41-4 (EZ)-6-oxo-2-ochtoden-1-yl trifluoroacetate 
• 82528-42-5 (EZ)-1-hydroxy-2-ochtoden-6-one 
• 30346-27-1 (E)-2-(3,3-Dimethylcyclohexylidene)ethanol 
• 121617-98-9 (Z)-2-ochtoden-1-ol tetrahydropyranyl ether 

Downstream Products

• 26532-24-1 (Z)-3,3-Dimethylcyclohexane-Δ^1,?-acetaldehyde 

Relevant articles and documents

THE STEREOSPECIFIC FORMATION OF AN EXOCYCLIC ALKENE BY A CONSECUTIVE RADICAL CYCLIZATION-ELEIMINATION

The iodovinylstannanes 4 and 5 were prepared by the conjugate addition of the tri-n-butyltin moiety to a substituted propiolic ester.Compounds 4 and 5 underwent a radical cyclization-elimination reaction to stereospecifically generate an exocyclic alkene.

SYNTHETIC STUDIES ON THE OCHTODANE TYPE TERPENES I. STEREOSELECTIVE CONSTRUCTION OF THE OCHTODANE SKELETON FROM MYRCENE.

The ochtodane skeleton, the Carbon framework of 1,1-dimethyl-3-ethylcyclohexane (1) was constructed highly stereoselectively by the acid-catalyzed (SnCl//4 or CF//3CO//2H) cyclization of the terminally functionalized myrcene derivatives, the benzenesulfenyl chloride adduct (7), the terminal beta -hydroxy sulfide (8) derived from 7, and myrcene 6,7-epoxide (10). The stereoselectivity of the 3-exo-double bond in 1 formed concomitantly in the cyclization reaction was found to depend remarkably upon the reaction temperture and the 85-94% of E-stereoselectivity was attained at minus 78 degree C. By the method, the ochtodane derivatives with the sulfur- or oxygen-functional groups on the C(6)-position were obtained.