26532-25-2

Basic information

• Product Name: GrandlureIII
• Synonyms: GrandlureIII;GRANDLURE IV;(E)-3,3-Dimethylcyclohexylideneacetaldehyde;[(E)-3,3-Dimethylcyclohexylidene]acetaldehyde;1-[(E)-Formylmethylene]-3,3-dimethylcyclohexane;trans-3,3-Dimethyl-Δ1,α-cyclohenaneacetaldehyde
• CAS NO: 26532-25-2
• Molecular Formula: C₁₀H₁₆O
• Molecular Weight: 152.23
• Mol File: 26532-25-2.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 226.6±9.0℃ (760 Torr)
• Flash Point: 95.6±11.0℃
• Appearance: /
• Density: 0.955±0.06 g/cm3 (20 ºC 760 Torr)
• Vapor Pressure: 0.081mmHg at 25°C
• Refractive Index: 1.4824 (22℃)
• CAS DataBase Reference: GrandlureIII(CAS DataBase Reference)
• NIST Chemistry Reference: GrandlureIII(26532-25-2)
• EPA Substance Registry System: GrandlureIII(26532-25-2)

Safety Data

• Hazardous Substances Data: 26532-25-2(Hazardous Substances Data)

Usage

InChI:InChI=1/C10H16O/c1-10(2)6-3-4-9(8-10)5-7-11/h5,7H,3-4,6,8H2,1-2H3/b9-5+

Upstream product

• 30346-27-1 (E)-2-(3,3-Dimethylcyclohexylidene)ethanol 
• 57559-99-6 Acetic acid 1-ethynyl-3,3-dimethyl-cyclohexyl ester 
• 82528-42-5 (EZ)-1-hydroxy-2-ochtoden-6-one 
• 82528-39-0 6-phenylthio-2-ochtoden-1-ol 
• 82528-41-4 (EZ)-6-oxo-2-ochtoden-1-yl trifluoroacetate 
• 121617-99-0 Formic acid 2-[4-hydroxy-3,3-dimethyl-cyclohex-(Z)-ylidene]-ethyl ester 
• 121618-01-7 (EZ)-6-oxo-2-ochtoden-1-yl formate 
• 82528-42-5 (2E)-1-hydroxy-2-ochtoden-6-one 
• 121618-03-9 (E)-6-oxo-2-ochtoden-1-yl 3,5-dinitrobenzoate 
• 30346-25-9 3,3-Dimethyl-E-cycloheylidenessigsaeuremethylester 
• 112381-71-2 (E)-8-Iodo-7,7-dimethyl-3-tributylstannanyl-oct-2-enoic acid methyl ester 
• 5629-80-1 (1-hydroxy-3,3-dimethyl-cyclohexyl)-acetic acid ethyl ester 
• 30346-22-6 3,3-Dimethyl-1-hydroxy-cyclohexylessigsaeure 

Downstream Products

• 170238-25-2 (3S,3aR,3bR,6aS,7aS)-3-{(R)-2-[3,3-Dimethyl-cyclohex-(E)-ylidene]-1-hydroxy-ethyl}-3a,3b,6a,7a-tetrahydro-3H-difuro[2,3-b;3',2'-d]furan-2-one 
• 170423-35-5 (3S,3aR,3bR,6aS,7aS)-3-{(S)-2-[3,3-Dimethyl-cyclohex-(E)-ylidene]-1-hydroxy-ethyl}-3a,3b,6a,7a-tetrahydro-3H-difuro[2,3-b;3',2'-d]furan-2-one 
• 170238-34-3 Acetic acid (2S,3S,3aS,3bR,6aS,7aS)-4-[2-[3,3-dimethyl-cyclohex-(E)-ylidene]-eth-(E)-ylidene]-2-hydroxy-5-oxo-octahydro-difuro[2,3-b;3',2'-d]furan-3-yl ester 
• 170238-27-4 C₁₈H₂₂O₅ 
• 170423-36-6 (3aR,3bR,6aS,7aS)-3-[2-[3,3-Dimethyl-cyclohex-(E)-ylidene]-eth-(Z)-ylidene]-3a,3b,6a,7a-tetrahydro-3H-difuro[2,3-b;3',2'-d]furan-2-one 
• 170238-26-3 (3aR,3bR,6aS,7aS)-3-[2-[3,3-Dimethyl-cyclohex-(E)-ylidene]-eth-(E)-ylidene]-3a,3b,6a,7a-tetrahydro-3H-difuro[2,3-b;3',2'-d]furan-2-one 
• 170238-33-2 Acetic acid (R)-2-[3,3-dimethyl-cyclohex-(E)-ylidene]-1-((3S,3aR,3bR,6aS,7aS)-2-oxo-2,3,3a,3b,6a,7a-hexahydro-difuro[2,3-b;3',2'-d]furan-3-yl)-ethyl ester 

Relevant articles and documents

Tandem Michael - Wittig - Horner reaction: One-pot synthesis of δ- substituted α,β-unsaturated carboxylic acid derivatives - application to a concise synthesis of (Z)- and (E)-ochtoden-1-al

A new tandem Michael-Wittig-Horner reaction has been developed to produce in high yields δ-substituted α,β-unsaturated esters, amides and lactones. The reaction has been successfully applied to a concise synthesis of (E)- and (Z)-ochtoden-1-als, component

THE STEREOSPECIFIC FORMATION OF AN EXOCYCLIC ALKENE BY A CONSECUTIVE RADICAL CYCLIZATION-ELEIMINATION

The iodovinylstannanes 4 and 5 were prepared by the conjugate addition of the tri-n-butyltin moiety to a substituted propiolic ester.Compounds 4 and 5 underwent a radical cyclization-elimination reaction to stereospecifically generate an exocyclic alkene.