265655-76-3Relevant articles and documents
Rhodium-catalyzed asymmetric hydrogenation of β-branched enamides for the synthesis of β-stereogenic amines
Zhang, Jian,Liu, Chong,Wang, Xingguang,Chen, Jianzhong,Zhang, Zhenfeng,Zhang, Wanbin
, p. 6024 - 6027 (2018/06/18)
Using a rhodium complex of a bisphosphine ligand (R)-SDP, β-branched simple enamides with a (Z)-configuration were hydrogenated to β-stereogenic amines in quantitative yields and with excellent enantioselectivities (88-96% ee).