2702-79-6

Basic information

• Product Name: 2-(p-Chlorobenzyl)cyclohexanone
• Synonyms: 2-(p-Chlorobenzyl)cyclohexanone;2-[(4-chlorophenyl)methyl]cyclohexan-1-one
• CAS NO: 2702-79-6
• Molecular Formula: C₁₃H₁₅ClO
• Molecular Weight: 222.7106
• Mol File: 2702-79-6.mol
• Article Data: 2

Chemical Properties

• Melting Point: 139-141 °C(Solv: ethyl acetate (141-78-6))
• Boiling Point: 333.7°Cat760mmHg
• Flash Point: 185.2°C
• Appearance: /
• Density: 1.152g/cm³
• Vapor Pressure: 0.000135mmHg at 25°C
• Refractive Index: 1.553
• CAS DataBase Reference: 2-(p-Chlorobenzyl)cyclohexanone(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(p-Chlorobenzyl)cyclohexanone(2702-79-6)
• EPA Substance Registry System: 2-(p-Chlorobenzyl)cyclohexanone(2702-79-6)

Safety Data

• Hazardous Substances Data: 2702-79-6(Hazardous Substances Data)

Usage

InChI:InChI=1/C13H15ClO/c14-12-7-5-10(6-8-12)9-11-3-1-2-4-13(11)15/h5-8,11H,1-4,9H2

Upstream product

• 39209-07-9 2-methylcyclohexanone O-methyl oxime 
• 13161-16-5 2-[hydroxy(4-chlorophenyl)methyl]cyclohexan-1-one 
• 104-88-1 4-chlorobenzaldehyde 
• 108-94-1 cyclohexanone 
• 1125-99-1 1-(1-Cyclohexen-1-yl)pyrrolidine 
• 104-83-6 1-Chloro-4-(chloromethyl)benzene 
• 121045-01-0 (E)-2-(4-chloro-phenylmethylene)-cyclohexanol 
• 31021-05-3 (E)-2-(4-chlorobenzylidene)cyclohexanone 

Downstream Products

• 144147-72-8 2-(4-Chloro-benzyl)-6-(2,2-dimethoxy-acetyl)-cyclohexanone 
• 2702-87-6 2-<4-Chlor-benzyl>-2-<2-cyan-aethyl>-cyclohexanon 
• 1770-35-0 3-<1-(4-Chlor-benzyl)-2-oxo-cyclohexyl>-propionsaeure 
• 144149-40-6 (E)-3-[7-(4-Chloro-benzyl)-2-(4-fluoro-phenyl)-4,5,6,7-tetrahydro-2H-indazol-3-yl]-propenal 
• 144148-17-4 7-(4-Chloro-benzyl)-2-(4-fluoro-phenyl)-4,5,6,7-tetrahydro-2H-indazole-3-carbaldehyde 

Relevant articles and documents

β-Arylation of oxime ethers using diaryliodonium salts through activation of inert C(sp 3)-H bonds using a palladium catalyst

An efficient method of selective β-arylation of oxime ethers was realized by using a palladium catalyst with diaryliodonium salts as the key arylation reagents. The reaction proceeded smoothly through the activation of inert C(sp3)-H bonds to give corresponding ketones and aldehydes. This convenient procedure can be successfully applied to construct new C(sp3)-C(sp2) bonds on a number of complex molecules derived from natural products and thus serves as a practical synthetic tool for direct late-stage C(sp3)-H functionalization.