27064-04-6

Basic information

• Product Name: S-(4-nitrophenyl) thioformate
• Synonyms: S-(4-nitrophenyl) thioformate
• CAS NO: 27064-04-6
• Molecular Weight: 183.188
• Mol File: 27064-04-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: S-(4-nitrophenyl) thioformate(CAS DataBase Reference)
• NIST Chemistry Reference: S-(4-nitrophenyl) thioformate(27064-04-6)
• EPA Substance Registry System: S-(4-nitrophenyl) thioformate(27064-04-6)

Safety Data

• Hazardous Substances Data: 27064-04-6(Hazardous Substances Data)

Upstream product

• 1849-36-1 para-nitrobenzenethiol 
• 2258-42-6 formyl acetic anhydride 
• 64-18-6 formic acid 

Downstream Products

• 84184-53-2 4-benzyloxycinnamaldehyde 
• 58095-77-5 (E)-3,4-methylenedioxycinnamaldehyde 
• 20432-35-3 3-(4-dimethylamino-phenyl)-propenal 
• 20884-05-3 (E)-3-(2-naphthyl)-2-propenal 
• 4549-82-0 (E)-2-methylcinnamaldehyde 
• 56578-35-9 4-methyl-cinnamaldehyde 
• 1075-77-0 (E)-4-chlorocinnamic aldehyde 
• 24654-55-5 trans-4-fluorocinnamaldehyde 
• 14371-10-9 (E)-3-phenylpropenal 
• 4370-87-0 2-methyl-2-phenyl-but-3-enal 
• 4312-87-2 formohydroxamic acid 
• 71-47-6 formate 
• 45797-13-5 4-nitrophenylthiolate 

Relevant articles and documents

Palladium-Catalyzed Formylation of Alkenylzinc Reagents with S-(4-Nitrophenyl) Thioformate

We report the synthesis of enal compounds by palladium-catalyzed formylation of alkenylzinc reagents with S-(4-nitrophenyl) thioformate. Various functional groups were tolerated in the present reaction. 1H NMR experiments revealed that the products had a non-protected formyl group, which can be utilized for further C–C bond formation reactions. We successfully achieved the one-pot synthesis of a 1,5-diene-3-ol compound via sequential formylation and allylation.