270902-68-6

Basic information

• Product Name: Carbamic acid, [(3S,6R)-hexahydro-6-hydroxy-2-oxo-1H-azepin-3-yl]-, 1,1-dimethylethyl ester
• CAS NO: 270902-68-6
• Molecular Formula: C11H20N2O4
• Molecular Weight: 244.291
• Mol File: 270902-68-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Carbamic acid, [(3S,6R)-hexahydro-6-hydroxy-2-oxo-1H-azepin-3-yl]-, 1,1-dimethylethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Carbamic acid, [(3S,6R)-hexahydro-6-hydroxy-2-oxo-1H-azepin-3-yl]-, 1,1-dimethylethyl ester(270902-68-6)
• EPA Substance Registry System: Carbamic acid, [(3S,6R)-hexahydro-6-hydroxy-2-oxo-1H-azepin-3-yl]-, 1,1-dimethylethyl ester(270902-68-6)

Safety Data

• Hazardous Substances Data: 270902-68-6(Hazardous Substances Data)

Upstream product

• 1268870-82-1 (2S)-methyl 6-(benzylamino)-2-[(tert-butoxycarbonyl)amino]-5-hydroxyhexanoate 

Downstream Products

• 270902-69-7 (3S,6R)-3-(tert-butoxycarbonyl)aminohexahydro-6-(cyclohexanecarbonyl)-oxy-2H-azepin-2-one 
• 104947-69-5 bengamide B 
• 334905-26-9 (3S,6S)-3-(tert-butyloxycarbonyl)aminohexahydro-6-(4-nitrophenylcarbonyl)oxy-2H-azepin-2-one 
• 374602-87-6 4-Decyloxy-benzoic acid (3R,6S)-6-{(R)-2-[(4R,5S,6R)-6-((E)-3,3-dimethyl-but-1-enyl)-5-hydroxy-2,2-dimethyl-[1,3]dioxan-4-yl]-2-methoxy-acetylamino}-7-oxo-azepan-3-yl ester 
• 374602-89-8 4-Decyl-benzoic acid (3R,6S)-6-{(R)-2-[(4R,5S,6R)-6-((E)-3,3-dimethyl-but-1-enyl)-5-hydroxy-2,2-dimethyl-[1,3]dioxan-4-yl]-2-methoxy-acetylamino}-7-oxo-azepan-3-yl ester 
• 1054637-47-6 3-Phenyl-propionic acid (3R,6S)-6-{(R)-2-[(4R,5S,6R)-6-((E)-3,3-dimethyl-but-1-enyl)-5-hydroxy-2,2-dimethyl-[1,3]dioxan-4-yl]-2-methoxy-acetylamino}-7-oxo-azepan-3-yl ester 
• 270902-51-7 (2R,3R,4S,5R,6E)-3,4,5-trihydroxy-2-methoxy-8,8-dimethyl-N-[(3S,6R)-hexahydro-2-oxo-6-(cyclohexylcarbonyl)oxy-2H-azepin-3-yl]non-6-enamide 
• 1053746-56-7 Benzoic acid (3R,6S)-6-{(R)-2-[(4R,5S,6R)-6-((E)-3,3-dimethyl-but-1-enyl)-5-hydroxy-2,2-dimethyl-[1,3]dioxan-4-yl]-2-methoxy-acetylamino}-7-oxo-azepan-3-yl ester 
• 270902-70-0 (3S, 6R)-3-aminohexahydro-6-(cyclohexanecarbonyl)oxy-2H-azepin-2-one 

Relevant articles and documents

Synthesis of 2-amino-5-hydroxycaprolactam derivatives mediated by E-selective olefination and asymmetric oxidation of the enol ether

The asymmetric synthesis of 2-amino-5-hydroxycaprolactam derivatives is essential for exploring the antitumor properties of ester-bearing bengamides. In this study, chiral caprolactam isomers were achieved on the basis of highly E-selective Wittig olefina